Element-element additions to unsaturated carbon-carbon bonds catalyzed by transition metal complexes

被引：502

作者：

Beletskaya, Irina ^{[1
]}

Moberg, Christina

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Lab Organoelecment Cpds, SU-119899 Moscow, Russia

[2] Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden

来源：

CHEMICAL REVIEWS | 2006年 / 106卷 / 06期

关键词：

D O I：

10.1021/cr050530j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review covers homo- and heterointerelement additions to alkynes, 1,3-dienes, 1,2-dienes, and alkenes, as well as additions to methylenecyclopropanes and vinylcyclopropanes, with the latter being covered together with alkenes. The literature up to 2005 is covered. It is shown that fundamental studies of oxidative additions of interelement compounds to low valent transition metal complexes and insertion of different types of unsaturated hydrocarbons have resulted in deep insight into mechanistic aspects as well as important synthetic methodology.

引用

页码：2320 / 2354

页数：35

共 243 条

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