Obtaining adsorbents from acid and acid-thermal activation of bentonite for chlorothalonil pesticide removal

被引:0
作者
Boudouara, Nadia [1 ]
Marouf, Reda [1 ]
Schott, Jacques [2 ]
机构
[1] Univ Mustapha Stambouli Mascara, Lab Mat Applicat & Environm, PB 305 Mamounia Rd, Mascara 29000, Algeria
[2] Univ Paul Sabatier, Lab Geosci Environm Toulouse, CNRS, UMR 5563,OMP, Toulouse, France
来源
WATER PRACTICE AND TECHNOLOGY | 2020年 / 15卷 / 03期
关键词
acid attack; adsorption; bentonite; chlorothalonil; themal activation; AQUEOUS-SOLUTION; WASTE-WATER; SURFACE MODIFICATION; METHYLENE-BLUE; CONGO-RED; ADSORPTION; SORPTION; CARBON; COPPER; DYE;
D O I
10.2166/wpt.2020.065
中图分类号
TV21 [水资源调查与水利规划];
学科分类号
081501 ;
摘要
Bentonite samples collected from M'Zila of Mostaganem (Algeria) were treated in first protocol with sulfuric acid at concentrations 1, 3 and 6N. The second protocol concerns the acid attack of bentonite combined with thermal treatment at temperatures of 100 and 200 degrees C. The obtained adsorbents were characterized by different analyses techniques such as chemical composition, X-ray diffraction (XRD), specific surface area and pH(PZC). The modified bentonites were used for removal of Chlorothalonil (Chl) from aqueous solution. The adsorption behavior of the pesticide was studied under different experimental conditions of pH, contact time, concentration of Chl and temperature of solution. The adsorption of Chl followed pseudo-second order kinetics and was described by the Freundlich equation. Thermodynamic study revealed that Chl adsorption was endothermic and physical in nature.
引用
收藏
页码:812 / 825
页数:14
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  • [21] Adsorption of chloridazon from aqueous solution on heat and acid treated sepiolites
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    Socías-Viciana, M
    Ureña-Amate, MD
    Cantos-Molina, A
    Villafranca-Sánchez, M
    [J]. WATER RESEARCH, 2005, 39 (09) : 1849 - 1857
  • [22] Levels and Seasonal Variability of Pesticides in the Rural Atmosphere of Southern Ontario
    Hayward, Stephen J.
    Gouin, Todd
    Wania, Frank
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2010, 58 (02) : 1077 - 1084
  • [23] Sorption of dye from aqueous solution by peat
    Ho, YS
    McKay, G
    [J]. CHEMICAL ENGINEERING JOURNAL, 1998, 70 (02) : 115 - 124
  • [24] Citation review of Lagergren kinetic rate equation on adsorption reactions
    Ho Y.-S.
    [J]. Scientometrics, 2004, 59 (1) : 171 - 177
  • [25] Chemical modification of commercial kaolin for mitigation of organic pollutants in environment via adsorption and generation of inorganic pesticides
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  • [27] Lagergren S., 1898, Kung Sven Veten Hand, V24, P1, DOI DOI 10.1007/BF01501332
  • [28] THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM.
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