SYNTHESIS, CHARACTERIZATION, AND NAKED-EYE SENSOR APPLICATION OF FULLY SUBSTITUTED UREA-BASED CYCLOTRIPHOSPHAZENE COMPOUND

被引：7
作者：
Ozay, Hava [1 ]
Yildirim, Mehmet [2 ]
Ozay, Ozgur [3 ]
机构：
[1] Canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept Chem, Inorgan Chem Lab, TR-17100 Canakkale, Turkey
[2] Canakkale Onsekiz Mart Univ, Fac Engn, Dept Mat Sci & Engn, TR-17020 Canakkale, Turkey
[3] Canakkale Onsekiz Mart Univ, Lapseki Vocat Sch, Dept Chem & Chem Proc Technol, TR-17800 Canakkale Lapseki, Turkey
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2015年 / 190卷 / 11期
关键词：
Phosphazene; naked-eye sensor; urea; hexapodal compound; fluoride anion; COLORIMETRIC RECEPTORS; ANION RECOGNITION; AQUEOUS-SOLUTION; F-IONS; FLUORIDE; THIOSEMICARBAZONES; CHEMOSENSOR; THIOUREA; CYANIDE; PHOSPHAZENE;
D O I：
10.1080/10426507.2015.1031752
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel sensor with a hexacenter containing nitrophenylurea groups on a cyclotriphosphazene core was synthesized by click reaction of N-propargyl-substituted urea with a hexaazide-substituted cyclotriphosphazene compound. It was characterized by spectroscopic techniques such as Fourier transform infrared spectroscopy, nuclear magnetic resonance, and mass spectroscopy. This compound was used for naked-eye and spectrophotometric detection of F- anions. The optical sensor properties of compound were investigated using ultraviolet-visible spectroscopy.
引用
收藏
页码：1865 / 1873
页数：9
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