Catalytic asymmetric semipinacol rearrangements

被引：113

作者：

Wang, Shao-Hua ^{[1
,2
,3
]}

Li, Bao-Sheng ^{[2
,3
]}

Tu, Yong-Qiang ^{[2
,3
]}

机构：

[1] Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[3] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 19期

关键词：

ENANTIOSELECTIVE ALPHA-FLUORINATION; HIGHLY EFFICIENT SYNTHESIS; BRONSTED ACID CATALYSIS; DIELS-ALDER REACTION; BETA-KETO-ESTERS; RING-EXPANSION; CARBONYL-COMPOUNDS; STEREOSELECTIVE CONSTRUCTION; MICHAEL ADDITION; ALLYLIC ALCOHOLS;

D O I：

10.1039/c3cc48547a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the past few decades, the semipinacol rearrangement has been widely applied in the field of organic synthesis. However, its catalytic asymmetric version has not caught much attention until the beginning of the 21st century. Significant breakthroughs have been made due to the efforts of organic chemists. These important progressions are summarized in this paper.

引用

页码：2393 / 2408

页数：16

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