Structures and Fluorescent Properties of Cadmium(II) Complexes with 1D and 2D Structures Based on Tridentate Benzimidazole Ligands

被引：5
|
作者：
Feng, Rui [1 ]
Hou, Yong [1 ]
Wu, Zhen-Zhen [1 ]
Yang, Yan [1 ]
Nie, Feng-Mei [1 ]
机构：
[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 11期
关键词：
2,6-Bis(benzimidazol-2-yl)pyridine; Cadmium; Bis(2-benzimidazolylmethyl)amine; Fluorescent properties; DNA-BINDING PROPERTIES; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ASSEMBLIES; COORDINATION FRAMEWORKS; METAL-COMPLEXES; X-RAY; POLYBENZIMIDAZOLE; RECOGNITION; DERIVATIVES; ZINC(II);
D O I：
10.1002/zaac.201400511
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cadmium(II) complexes [CdL1(m-nba)(2)] (1), [CdL1(p-nba)(2)]center dot C2H5OH (2), [CdL2(p-nba)(2)]center dot CH3OH (3), and [CdL2(p-nbat)(2)] (4) containing the ligands L1 and L2 [L1 = 2,6-bis(benzimidazol-2yl) pyridine, L2 = bis(2-benzimidazolylmethyl) amine] were synthesized and characterized (m-nba, p-nba, and p-nbat are the anions of pnitrobenzoic acid, m-nitrobenzoic acid, and p-nitrobenzeneacetic acid, respectively). The complexes were investigated by X-ray single crystal diffraction, elemental analysis as well as IR and fluorescence spectroscopy. Compounds 1-3 contain a distorted pentagonal bipyramidal coordination sphere with Cd-II coordinated by two carboxylate ligands in bidentate-chelating mode, whereas complex 4 exhibits a distorted octahedral arrangement with one carboxylate ligand in bidentate-chelating and the other in monodentate coordination mode. 1 and 2 form a 1D chain interplayed by hydrogen bonding and strong pi-pi stacking interactions. 3 and 4 vary from 1D chain into 2D single-layer and double-layer networks because of more extensive hydrogen bonding interactions. The complexes show emission maxima in the blue region in the solid state and emission bands are red-shifted compared to those of the free ligands.
引用
收藏
页码：1918 / 1925
页数：8
相关论文
共 50 条
  • [1] Structures and fluorescent properties of picolinato zinc(II) and cadmium(II) complexes based on tridentate and tetradentate benzimidazole ligands
    Feng, Rui
    Huang, Fang-Fang
    Yuan, Jia-Li
    Lu, Zheng
    Fang, Tao
    Nie, Feng-Mei
    JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (24) : 3776 - 3791
  • [2] Four 1D and 2D Cadmium(II) Complexes Based on Different Anions and Two Modified Bipyridyl Ligands: Syntheses, Structures, Thermogravimetric, and Fluorescent Properties
    Li, Linke
    Zhao, Jingjing
    Wang, Changhong
    Yang, Sisi
    Hou, Hongwei
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (01): : 187 - 194
  • [3] Syntheses, structures, and properties of two novel cadmium coordination polymers with 1D and 2D structures
    Yan, Li
    Li, Chuanbi
    Zhu, Dongsheng
    Xu, Lin
    JOURNAL OF MOLECULAR STRUCTURE, 2011, 1002 (1-3) : 172 - 178
  • [4] Two Zinc(II) Complexes with 1D Chain and 2D Layer Directed by Competitive Coordination of the Mixed Ligands: Syntheses, Crystal Structures, and Fluorescent Properties
    Dai, Pei-Xia
    Zhao, Hong
    Yang, En-Cui
    Zhao, Xiao-Jun
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (08) : 1163 - 1168
  • [5] From 1D to 2D coordination polymers based on benzimidazole and dicarboxylate: Syntheses, structures, and fluorescence properties
    Liu, Zhaolong
    Xie, Yueyue
    Huang, Nannan
    Dou, Zilin
    Gao, Wei
    Wu, Huilu
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1321
  • [6] Syntheses and structures of 1D, 2D, 3D cadmium(II) coordination polymers with oxalate and aromatic co-ligands
    Xia, SQ
    Hu, SM
    Dai, JC
    Wu, XT
    Fu, ZY
    Zhang, HJ
    Du, WX
    POLYHEDRON, 2004, 23 (06) : 1003 - 1009
  • [7] 2D extended supramolecular structures via π-π interactions of 1D coordination polymers of cadmium(II) complexes of arylazoimidazole using azido and thiocyanato bridging ligands
    Chand, B
    Ray, U
    Mostafa, G
    Lu, TH
    Sinha, C
    POLYHEDRON, 2004, 23 (10) : 1669 - 1676
  • [8] Syntheses, Crystal Structures and Fluorescent Properties of Two 2D Cadmium(II) Coordination Polymers
    Guo Hai-Fu
    Lei Jia-Mei
    Ma De-Yun
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2015, 31 (12) : 2385 - 2392
  • [9] Effects of the Auxiliary Ligands on the Structures of Diphenate Complexes: From 1D Helical Chain to 2D Network
    Gou, Lei
    Li, Li
    Li, Jian-Li
    Fan, Xiao-Yong
    Li, Dong-Lin
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (08): : 1591 - 1595
  • [10] Chiral 1D and 2D assembly structures of self-complementary copper(II) complexes with imidazole-containing ligands
    Matsumoto, N
    Katsuki, I
    Motoda, Y
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 342 (342): : 177 - 184
12345