A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions

被引：38
作者：
Smith, K
Lock, S
El-Hiti, GA
Wada, M
Miyoshi, N
机构：
[1] Univ Coll Swansea, Ctr Clean Chem, Dept Chem, Swansea SA2 8PP, W Glam, Wales
[2] Univ Tokushima, Fac Integrated Arts & Sci, Dept Chem, Tokushima 770, Japan
[3] Tanta Univ, Fac Sci, Dept Chem, Tanta 31527, Egypt
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 06期
关键词：
D O I：
10.1039/b400179f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new and convenient procedure for synthesis of homoallylic alcohols in generally good to excellent yields has been developed. The bismuth-mediated Barbier-type allylation of aldehydes ( aromatic, aliphatic, alicyclic and heterocyclic) with allyl bromide has been carried out smoothly in water in the presence of fluoride ions.
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页码：935 / 938
页数：4
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