Heterogeneity in cellulose pyrolysis indicated from the pyrolysis in sulfolane

被引：42

作者：

Kawamoto, H ^{[1
]}

Saka, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2006年 / 76卷 / 1-2期

关键词：

cellulose; pyrolysis; mechanism; heterogeneous; crystalline; non-crystalline; sulfolane;

D O I：

10.1016/j.jaap.2005.12.011

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In sulfolane (tetramethylene sulfone), which is a good solvent for the primary product, levoglucosan, cellulose is pyrolyzed completely into soluble products without forming any char. Residues during pyrolysis in sulfolane at 200, 240 and 330 degrees C were obtained always as colorless noncarbonized substances. From the change in the crystallinity and crystallite size as compared with the ordinary pyrolysis, a heterogeneous mechanism is indicated for cellulose pyrolysis, starting from a molecule which is less stabilized due to lack of some intermolecular interactions. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：280 / 284

页数：5

共 50 条

[31] Experimental and kinetic modelling investigation on the effects of crystallinity on cellulose pyrolysis [J].

Leng, E. ;

Ferreiro, A. I. ;

Liu, T. ;

Gong, X. ;

Costa, M. ;

Li, X. ;

Xu, M. .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2020, 152

[32] On-line catalytic cracking of vapors from cellulose fast pyrolysis [J].

Li, Pan ;

Li, Di ;

Sui, Haiqing ;

Shao, Jing'ai ;

Wang, Xianhua ;

Chen, Hanping .

Huagong Xuebao/CIESC Journal, 2015, 66 (10) :4131-4137

[33] Investigations on the effect of metal ions on the products obtained from the pyrolysis of cellulose [J].

Klampfl, Christian W. ;

Breuer, Gerold ;

Schwarzinger, Clemens ;

Koell, Berndt .

ACTA CHIMICA SLOVENICA, 2006, 53 (04) :437-443

[34] Acceleration of cellulose co-pyrolysis with polymer [J].

Matsuzawa, Y ;

Ayabe, M ;

Nishino, J .

POLYMER DEGRADATION AND STABILITY, 2001, 71 (03) :435-444

[35] Fermentation of cellulose pyrolysis oil by a Clostridial bacterium [J].

Buendia-Kandia, F. ;

Greenhalf, C. ;

Barbiero, C. ;

Guedon, E. ;

Briens, C. ;

Berruti, F. ;

Dufour, A. .

BIOMASS & BIOENERGY, 2020, 143

[36] Investigation of property of biochar in staged pyrolysis of cellulose [J].

Li, Dianqiang ;

Li, Chao ;

Fan, Mengjiao ;

Shao, Yuewen ;

Sun, Yifan ;

Zhang, Lijun ;

Zhang, Shu ;

Huang, Yong ;

Li, Bin ;

Wang, Shuang ;

Hu, Xun .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2023, 172

[37] A UNIFIED, GLOBAL-MODEL FOR THE PYROLYSIS OF CELLULOSE [J].

DIEBOLD, JP .

BIOMASS & BIOENERGY, 1994, 7 (1-6) :75-85

[38] A Logistic Approach for Kinetics of Isothermal Pyrolysis of Cellulose [J].

Lopez-Beceiro, Jorge ;

Diaz-Diaz, Ana Maria ;

alvarez-Garcia, Ana ;

Tarrio-Saavedra, Javier ;

Naya, Salvador ;

Artiaga, Ramon .

PROCESSES, 2021, 9 (03)

[39] The dependence of pyrolysis behavior on the crystal state of cellulose [J].

Zhang, Jiaxi ;

Luo, Jia ;

Tong, Dongmei ;

Zhu, Liangfang ;

Dong, Linlin ;

Hu, Changwei .

CARBOHYDRATE POLYMERS, 2010, 79 (01) :164-169

[40] Review of Reactions and Molecular Mechanisms in Cellulose Pyrolysis [J].

Kawamoto, Haruo .

CURRENT ORGANIC CHEMISTRY, 2016, 20 (23) :2444-2457

← 1 2 3 4 5 →