First example of the ribbed-functionalized iron(ii) clathrochelate with six pendante closo-borate substituents

被引：13

作者：

Kuznetsov, N. T. ^{[2
]}

Belaya , I. G. ^{[1
]}

Dolganov, A. V. ^{[1
]}

Zelinskii, G. E. ^{[1
]}

Matveev, E. Yu. ^{[2
]}

Zhizhin, K. Yu. ^{[2
]}

Voloshin, Ya. Z. ^{[1
]}

Bubnov, Yu. N. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

macrocyclic compounds; clathrochelates; iron complexes; closo-borates; boron neutron capture therapy; COMPLEXES;

D O I：

10.1007/s11172-011-0387-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The nucleophilic substitution of the reactive chlorine atoms of the n-butylboron-capped hexachlorine-containing clathrochelate precursor with the thiol-terminated closo-decaborate (PPh4)(2)[B10H9OCH2CH2OCH2CH2SH] in the presence of triethylamine afforded the closo-decaborate-containing clathrochelate dodecaanion [Fe{[(B10H9OCH2CH2OCH2CH2S)(2)Gm](3)-(BBun)(2)}](12-), which was isolated in the form of its tetraphenylphosphonium and sodium salts. The complexes obtained were characterized using elemental analysis, UV-VIS, H-1, B-11, and C-13{H-1} NMR, and IR spectroscopies.

引用

页码：2518 / 2521

页数：4

共 11 条

[1] VIBRATIONAL SPECTROSCOPY OF CARBORANES AND PARENT BORANES AND ITS CAPABILITIES IN CARBORANE CHEMISTRY [J].

LEITES, LA .

CHEMICAL REVIEWS, 1992, 92 (02) :279-323

[2]

Lisovskii MV, 2005, RUSS J INORG CHEM+, V50, P20

[3]

Mann C. K., 1970, ELECTROCHEMICAL REAC, P434

[4]

Matveev E.Yu., 2010, RUSS CHEM B, P544

[5] ELECTROCHEMISTRY OF BORON-COMPOUNDS [J].

MORRIS, JH ;

GYSLING, HJ ;

REED, D .

CHEMICAL REVIEWS, 1985, 85 (01) :51-76

[6] Polyhedral Boranes for Medical Applications: Current Status and Perspectives [J].

Sivaev, Igor B. ;

Bregadze, Vladimir V. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (11) :1433-1450

[7] The chemistry of neutron capture therapy [J].

Soloway, AH ;

Tjarks, W ;

Barnum, BA ;

Rong, FG ;

Barth, RF ;

Codogni, IM ;

Wilson, JG .

CHEMICAL REVIEWS, 1998, 98 (04) :1515-1562

[8] Cage complexes as a molecular scaffold for polyfunctional and polytopic systems:: Synthesis of the first closo-borate iron(II) clathrochelate [J].

Voloshin, Ya. Z. ;

Varzatskii, O. A. ;

Zhizhin, K. Yu. ;

Kuznetsov, N. T. ;

Bubnov, Yu. N. .

RUSSIAN CHEMICAL BULLETIN, 2006, 55 (01) :22-25

[9] Prediction of the geometry of low-spin iron(II) complexes using a modified concept of partial quadrupole splitting (PQS): Advantages and limitations [J].

Voloshin, YZ ;

Polshin, EV ;

Nazarenko, AY .

HYPERFINE INTERACTIONS, 2002, 141 (1-4) :309-320

[10] Triribbed-functionalized clathrochelate iron(II) dioximates as a new and promising tool to obtain polynucleating and polynuclear compounds with improved properties [J].

Voloshin, YZ ;

Varzatskii, OA ;

Kron, TE ;

Belsky, VK ;

Zavodnik, VE ;

Strizhakova, NG ;

Palchik, AV .

INORGANIC CHEMISTRY, 2000, 39 (09) :1907-1918

← 1 2 →