Chemical speciation of heavy metals in the Tigris River sediment

被引:43
作者
Gümgüm, B [1 ]
Öztürk, G [1 ]
机构
[1] Dicle Univ, Dept Chem, TR-21280 Diyarbakir, Turkey
来源
CHEMICAL SPECIATION AND BIOAVAILABILITY | 2001年 / 13卷 / 01期
关键词
heavy metals; microwave digestion; sediment; sequential extraction; speciation;
D O I
10.3184/095422901782775453
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
After determination of total heavy metal concentrations in Tigris river sediments, a Tessier sequential extraction technique and a modified form using a microwave heating procedure were applied. Recoveries of total heavy metals from the sediment samples using the microwave and conventional techniques were reasonably comparable, in spite of a big difference in time required. 44-46% of Co, 24-36% of Cu, 69-81 % of Ni, and 55-73% of Zn were found in the residual fraction (i.e. not bioavailable).
引用
收藏
页码:25 / 29
页数:5
相关论文
共 41 条
[1]   ELEMENTAL ANALYSIS OF SOLID ENVIRONMENTAL-SAMPLES BY LOW-TEMPERATURE PLASMA ASHING AND MICROWAVE ACID DIGESTION [J].
ACHILLI, M ;
BARBAN, R ;
ZUCCHI, B ;
MARTINOTTI, W .
WATER AIR AND SOIL POLLUTION, 1991, 57-8 :495-503
[2]   Heavy metal concentrations in water and bottom sediments of a Mexican reservoir [J].
Avila-Pérez, P ;
Balcázar, M ;
Zarazúa-Ortega, G ;
Barceló-Quintal, I ;
Díaz-Delgado, C .
SCIENCE OF THE TOTAL ENVIRONMENT, 1999, 234 (1-3) :185-196
[3]   Metal speciation in Jhanji River sediments [J].
Baruah, NK ;
Kotoky, P ;
Bhattacharyya, KG ;
Borah, GC .
SCIENCE OF THE TOTAL ENVIRONMENT, 1996, 193 (01) :1-12
[4]  
Chapman PM, 1998, CAN J FISH AQUAT SCI, V55, P2221, DOI 10.1139/f98-145
[5]  
*COMM EUR COMM, 1983, 8837 BRC EUR EN
[6]   EVALUATION OF A SEQUENTIAL EXTRACTION PROCEDURE FOR THE SPECIATION OF HEAVY-METALS IN SEDIMENTS [J].
DAVIDSON, CM ;
THOMAS, RP ;
MCVEY, SE ;
PERALA, R ;
LITTLEJOHN, D ;
URE, AM .
ANALYTICA CHIMICA ACTA, 1994, 291 (03) :277-286
[7]   Experimental studies of impacts of harbour sediments resuspension to marine invertebrates larvae: Bioavailability of Cd, Cu, Pb and Zn and toxicity [J].
Fichet, D ;
Radenac, G ;
Miramand, P .
MARINE POLLUTION BULLETIN, 1998, 36 (07) :509-518
[8]   Comparison of microwave-assisted acid leaching techniques for the determination of heavy metals in sediments, soils, and sludges [J].
Florian, D ;
Barnes, RM ;
Knapp, G .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1998, 362 (7-8) :558-565
[9]  
Forstner U., 1991, METALS THEIR COMPOUN, P379
[10]   Microwave desorption treatment after the oxidation step in Tessier's sequential extraction scheme [J].
Ginepro, M ;
Gulmini, M ;
Ostacoli, G ;
Zelano, V .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1996, 63 (02) :147-152