A new 3D Keggin-POM based metal-organic framework of Cu and H2biim: Assembly and properties of fluorescence and electrochemistry

被引：10

作者：

Shi, Zhenyu ^{[1
,2
]}

Peng, Jun ^{[1
]}

Yu, Xia ^{[1
]}

Shen, Yan ^{[1
]}

Zhang, Zheyu ^{[1
]}

Alimaje, Kundawlet ^{[1
]}

Wang, Xiang ^{[1
]}

机构：

[1] NE Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Dept Chem, Changchun 130024, Jilin, Peoples R China

[2] Xingyi Normal Coll Nationalities, Xingyi 562400, Guizhou, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 28卷

基金：

美国国家科学基金会;

关键词：

Keggin; Metal-organic framework; Hydrothermal synthesis; Electrochemical property; CRYSTAL-STRUCTURE; ARCHITECTURES; POLYMER;

D O I：

10.1016/j.inoche.2012.10.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D Keggin-based metal-organic framework consisting of two kinds of Cu-H(2)biim chains, Cu-10(H-2-biim)(10)(PW12O40)(2)(OH)(4)center dot 5H(2)O 1 (H(2)biim=2,2'-biimidazole), has been synthesized under hydrothermal conditions. The TGA and PXRD measurements show that the framework is stable after removal of the guest water molecules. In addition, the luminescent and electrochemical properties of 1 have also been investigated. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.

引用

页码：85 / 89

页数：5

共 29 条

[1] Three-Dimensional Architectures Based on Lanthanide-Substituted Double-Keggin-Type Polyoxometalates and Lanthanide Cations or Lanthanide-Organic Complexes [J].

An, Haiyan ;

Han, Zhengbo ;

Xu, Tieqi .

INORGANIC CHEMISTRY, 2010, 49 (24) :11403-11414

[2] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[3]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[4]

2-U

[5] A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].

Chen, BL ;

Liang, CD ;

Yang, J ;

Contreras, DS ;

Clancy, YL ;

Lobkovsky, EB ;

Yaghi, OM ;

Dai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393

[6] Polyoxometalate-based molecular materials [J].

Coronado, E ;

Gomez-Garcia, CJ .

CHEMICAL REVIEWS, 1998, 98 (01) :273-296

[7] Brightly phosphorescent trinuclear copper(I) complexes of pyrazolates: Substituent effects on the supramolecular structure and photophysics [J].

Dias, HVR ;

Diyabalanage, HVK ;

Eldabaja, MG ;

Elbjeirami, O ;

Rawashdeh-Omary, MA ;

Omary, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) :7489-7501

[8] Ligand and counterion control of Ag(I) architectures:: Assembly of a {Ag8} ring cluster mediated by hydrophobic and Ag•••Ag interactions [J].

Fielden, John ;

Long, De-liang ;

Slawin, Alexandra M. Z. ;

Kogerler, Paul ;

Cronin, Leroy .

INORGANIC CHEMISTRY, 2007, 46 (22) :9090-9097

[9] Photoluminescence properties of multinuclear copper(I) compounds [J].

Ford, PC ;

Cariati, E ;

Bourassa, J .

CHEMICAL REVIEWS, 1999, 99 (12) :3625-3647

[10] An Ionothermal Synthetic Approach to Porous Polyoxometalate-Based Metal-Organic Frameworks [J].

Fu, Hai ;

Qin, Chao ;

Lu, Ying ;

Zhang, Zhi-Ming ;

Li, Yang-Guang ;

Su, Zhong-Min ;

Li, Wen-Liang ;

Wang, En-Bo .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (32) :7985-7989

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