Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichioro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene

被引：19
作者：
Atioglu, Zeliha [1 ]
Akkurt, Mehmet [2 ]
Shikhaliyev, Namiq Q. [3 ]
Suleymanova, Gulnar T. [3 ]
Bagirova, Khanim N. [3 ]
Toze, Flavien A. A. [4 ]
机构：
[1] Cappadocia Univ, Ilke Educ & Hlth Fdn, Cappadocia Vocat Coll, Med Imaging Tech Program, TR-50420 Urgup, Nevsehir, Turkey
[2] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey
[3] Baku State Univ, Organ Chem Dept, Z Xalilov Str 23, Baku 1148, Azerbaijan
[4] Univ Douala, Dept Chem, Fac Sci, POB 24157, Douala, Cameroon
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷
关键词：
crystal structure; 4-fluorophenyl ring; nitro-substituted benzene ring; hydrogen bonding; Hirshfeld surface analysis; INTERMOLECULAR INTERACTIONS; QUANTITATIVE-ANALYSIS; HYDROGEN-BONDS; X-RAY; TETREL; HALOGEN; COMPLEXES; PNICOGEN; DESIGN;
D O I：
10.1107/S2056989019000707
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C14H8Cl2FN3O2, the 4-fluorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)degrees. In the crystal, molecules are linked by C-H center dot center dot center dot O hydrogen bonds into chains running parallel to the c axis. The crystal packing is further stabilized by C-Cl center dot center dot center dot pi, C-F center dot center dot center dot pi and N-O center dot center dot center dot-pi interactions. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H center dot center dot center dot O/O center dot center dot center dot H (15.5%), H center dot center dot center dot H (15.3%), Cl center dot center dot center dot H/H center dot center dot center dot Cl (13.8%), C center dot center dot center dot H/H center dot center dot center dot C (9.5%) and F center dot center dot center dot H/H center dot center dot center dot F (8.2%) interactions.
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收藏
页码：237 / +
页数：9
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