Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichioro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene

被引：19

作者：

Atioglu, Zeliha ^{[1
]}

Akkurt, Mehmet ^{[2
]}

Shikhaliyev, Namiq Q. ^{[3
]}

Suleymanova, Gulnar T. ^{[3
]}

Bagirova, Khanim N. ^{[3
]}

Toze, Flavien A. A. ^{[4
]}

机构：

[1] Cappadocia Univ, Ilke Educ & Hlth Fdn, Cappadocia Vocat Coll, Med Imaging Tech Program, TR-50420 Urgup, Nevsehir, Turkey

[2] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey

[3] Baku State Univ, Organ Chem Dept, Z Xalilov Str 23, Baku 1148, Azerbaijan

[4] Univ Douala, Dept Chem, Fac Sci, POB 24157, Douala, Cameroon

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷

关键词：

crystal structure; 4-fluorophenyl ring; nitro-substituted benzene ring; hydrogen bonding; Hirshfeld surface analysis; INTERMOLECULAR INTERACTIONS; QUANTITATIVE-ANALYSIS; HYDROGEN-BONDS; X-RAY; TETREL; HALOGEN; COMPLEXES; PNICOGEN; DESIGN;

D O I：

10.1107/S2056989019000707

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C14H8Cl2FN3O2, the 4-fluorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)degrees. In the crystal, molecules are linked by C-H center dot center dot center dot O hydrogen bonds into chains running parallel to the c axis. The crystal packing is further stabilized by C-Cl center dot center dot center dot pi, C-F center dot center dot center dot pi and N-O center dot center dot center dot-pi interactions. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H center dot center dot center dot O/O center dot center dot center dot H (15.5%), H center dot center dot center dot H (15.3%), Cl center dot center dot center dot H/H center dot center dot center dot Cl (13.8%), C center dot center dot center dot H/H center dot center dot center dot C (9.5%) and F center dot center dot center dot H/H center dot center dot center dot F (8.2%) interactions.

引用

页码：237 / +

页数：9

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