Characterization of Hydrazinium 3,5-Dinitroamine-1,2,4-triazole

被引：3

作者：

Cui, Kejian ^{[1
]}

Meng, Zihui ^{[1
]}

Xu, Zhibin ^{[1
]}

Xue, Min ^{[1
]}

Lin, Zhihui ^{[2
]}

Wang, Bozhou ^{[2
]}

Ge, Zhongxue ^{[2
]}

Qin, Guangmin ^{[2
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] Xian Modern Chem Res Inst, Xian, Peoples R China

来源：

JOURNAL OF ENERGETIC MATERIALS | 2014年 / 32卷

关键词：

energetic material; hydrazinium 3,5-dinitroamine-1,2,4-triazole; triazole; characterization; DERIVATIVES; CHEMISTRY;

D O I：

10.1080/07370652.2013.828246

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The structure of hydrazinium 3,5-dinitroamine-1,2,4-triazole (HDNAT) was investigated with infrared (IR), mass spectrometry, C-13-NMR, scanning electron microscopy (SEM), and X-ray crystallography. The crystal density of HDNAT was determined as 1.91g/cm(3) using X-ray diffraction. The crystal belongs to a monoclinic system with the space group P2(1). The thermal decomposition process of HDNAT was investigated via thermogravimetry-differential thermal analysis (TG-DTA) at a heating rate of 10K/min and differential scanning calorimetry (DSC) under nonisothermal conditions. The decomposition kinetic and thermodynamic parameters were obtained by the Kissinger and Ozawa method. HDNAT can be analyzed by using a C18 high-performance liquid chromatography (HPLC) column with water : acetonitrile : trifluoroacetic acid (97/3/0.1, v/v/v) as the mobile phase and a capacity factor of 1.33.

引用

页码：S60 / S70

页数：11

共 22 条

[1]

Chang JJ, 2011, CHEM J CHINESE U, V32, P1970

[2] Synthesis and Characterization of 1-Nitroguanyl-3-nitro-5-amino-1,2,4-triazole [J].

Chavez, David E. ;

Parrish, Damon A. .

PROPELLANTS EXPLOSIVES PYROTECHNICS, 2012, 37 (05) :536-539

[3] 1,2,4-triazolium-cation-based energetic salts [J].

Darwich, Chaza ;

Klapoetke, Thomas M. ;

Sabate, Charles Miro .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (19) :5756-5771

[4] Nitrogen-Rich Bis-1,2,4-triazoles-A Comparative Study of Structural and Energetic Properties [J].

Dippold, Alexander A. ;

Klapoetke, Thomas M. .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (52) :16742-16753

[5]

Duan B. R., 1987, China Patent, Patent No. 85105516

[6] Design and synthesis of energetic materials [J].

Fried, LE ;

Manaa, MR ;

Pagoria, PF ;

Simpson, RL .

ANNUAL REVIEW OF MATERIALS RESEARCH, 2001, 31 :291-321

[7]

Fu Z. J., 1985, CHINESE J STRUCTURE, V3, P206

[8] Azole-Based Energetic Salts [J].

Gao, Haixiang ;

Shreeve, Jean'ne M. .

CHEMICAL REVIEWS, 2011, 111 (11) :7377-7436

[9]

Gao X. R., 1998, HUOZHAYAO XUEBAO, V3, P48

[10] THE HYDRAZINOLYSIS OF NITROGUANIDINE IN ALCOHOLIC SYSTEMS - PREPARATION AND REACTIONS OF 1,6-DINITROBIGUANIDINE [J].

HENRY, RA ;

SKOLNIK, S ;

SMITH, GBL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (04) :955-962

← 1 2 3 →