Conversion of 5-hydroxymethylfurfural to chemicals: A review of catalytic routes and product applications

被引:115
|
作者
Kong, Qing-Shan [1 ,2 ]
Li, Xing-Long [1 ]
Xu, Hua-Jian [2 ]
Fu, Yao [1 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, IChEM,Inst Energy,Hefei Comprehens Natl Sci Ctr,D, CAS Key Lab Urban Pollutant Convers,Anhui Prov Ke, Hefei 230026, Peoples R China
[2] Hefei Univ Technol, Sch Food & Biol Engn, Hefei 230009, Peoples R China
基金
中国国家自然科学基金;
关键词
5-Hydroxymethylfurfural; Platform chemicals; Hydrogenation; Catalytic conversion; Furan derivatives; Material monomers; EFFICIENT AEROBIC OXIDATION; ONE-POT SYNTHESIS; LIQUID FUEL 2,5-DIMETHYLFURAN; BIOMASS-DERIVED CHEMICALS; BAYLIS-HILLMAN REACTION; PD ALLOY NANOPARTICLES; RICH FOOD WASTE; 2,5-FURANDICARBOXYLIC ACID; SELECTIVE HYDROGENATION; REDUCTIVE ETHERIFICATION;
D O I
10.1016/j.fuproc.2020.106528
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Biomass is the sole renewable organic carbon resource in nature. Conversion of Biomass can produce a series of platform molecules. As an essential multi-purpose bioderived furanic platform compound, 5-hydroxymethylfurfural (HMF) can be effectively transformed into a variety of value-added derivatives due to its rich chemistry and potential availability, which is an ideal renewable alternative to fossil fuels. This review highlights recent advances in the development of efficient catalytic systems for the conversion of HMF, especially heterogeneous catalysts. Heterogeneous catalysts have advantages in facile separation and recovery, tunable performance by adjusting catalyst structures. Simultaneously, we mainly focus on the application of downstream products in material monomers, pharmaceutical intermediates, and fuels. Furthermore, a few potential research trends are also proposed, in order to provide some useful ideas for the further exploration of the utilization and conversion of HMF in a much simple, efficient, and economical way.
引用
收藏
页数:21
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