The effect of organoclay contents on morphological characterization, mechanical and thermal properties of epoxidized natural rubber-50 toughened polyamide 6 nanocomposites

被引:8
|
作者
Nouparvar, Hamed [1 ]
Hassan, Azman [1 ]
Mohamad, Zurina [1 ]
Wahit, Mat Uzir [1 ]
Roozbahani, Fatemeh [2 ]
机构
[1] Univ Teknol Malaysia, Dept Polymer Engn, Fac Chem Engn, Skudai 81310, Johor, Malaysia
[2] Univ Teknol Malaysia, Fac Biosci & Med Engn, Skudai 81300, Johor, Malaysia
关键词
epoxidized natural rubber-50; montmorillonite; nanocomposites; polyamide; 6; toughening; SILICATE NANOCOMPOSITES; PHASE MORPHOLOGY; OCTENE COPOLYMER; BEHAVIOR; NYLON-6; BLENDS; CLAY;
D O I
10.1515/polyeng-2013-0066
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanocomposites consisting of polyamide 6 (PA6) matrix with epoxidized natural rubber-50 (ENR-50) and organoclay-modified montmorillonite (OMMT) were prepared by melt blending in a twin-screw extruder followed by injection molding. The influence of varying amounts (0-6 phr) of OMMT loadings on ENR-50 (10 wt.%) toughened PA6 nanocomposites was examined. Morphological characterizations and mechanical and thermal properties of the blend and nanocomposites were investigated. The addition of OMMT resulted in an increase in tensile strength and modulus, while impact strength and elongation at break reduced. Thermal study revealed no significant change in thermal properties with OMMT loadings. Exfoliated structure was observed from X-ray diffraction (XRD) patterns for <4 phr OMMT and was confirmed by transmission electron microscopy (TEM) images.
引用
收藏
页码:59 / 68
页数:10
相关论文
共 50 条
  • [1] Epoxidized natural rubber-50 toughened polyamide 6 nanocomposites: The effect of epoxidized natural rubber-50 contents on morphological characterization, mechanical and thermal properties
    Nouparvar, Hamed
    Hassan, Azman
    Mohamad, Zurina
    Wahit, Mat Uzir
    JOURNAL OF ELASTOMERS AND PLASTICS, 2014, 46 (03) : 269 - 283
  • [2] Novel epoxidized natural rubber toughened polyamide 6/halloysite nanotubes nanocomposites
    Sharif, Noor Fadzliana Ahmad
    Mohamad, Zurina
    Hassan, Azman
    Wahit, Mat Uzir
    JOURNAL OF POLYMER RESEARCH, 2012, 19 (01)
  • [3] Epoxidized natural rubber toughened polyamide 6/organically modified montmorillonite nanocomposites
    Balakrishnan, Harintharavimal
    Nematzadeh, Navid
    Wahit, Mat Uzir
    Hassan, Azman
    Imran, Muhammad
    JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2014, 27 (03) : 395 - 412
  • [4] The effect of rubber type and rubber functionality on the morphological and mechanical properties of rubber-toughened polyamide 6/polypropylene nanocomposites
    Wahit, Mat Uzir
    Hassan, Azman
    Ishak, Zainal Ariffin Mohd
    Rahmat, Abdul Razak
    Othman, Norhayani
    POLYMER JOURNAL, 2006, 38 (08) : 767 - 780
  • [5] Mechanical and thermomechanical properties of polyamide 6/Brazilian organoclay nanocomposites
    da Paz, Rene Anisio
    Damiao Leite, Amanda Melissa
    Araujo, Edcleide Maria
    Medeiros, Vanessa da Nobrega
    Alves de Melo, Tomas Jeferson
    Pessan, Luiz Antonio
    POLIMEROS-CIENCIA E TECNOLOGIA, 2016, 26 (01): : 52 - 60
  • [6] Mechanical and Thermal Properties of Polyamide 6 Nanocomposite Toughened with Epoxidised Natural Rubber-25
    Navid, Nematzadeh
    Mat, Uzir Wahit
    Azman, Hassan
    Shaya, Mahmoudian
    COMPOSITE SCIENCE AND TECHNOLOGY, PTS 1 AND 2, 2011, 471-472 : 518 - 523
  • [7] The Effect of Rubber Type and Rubber Functionality on the Morphological and Mechanical Properties of Rubber-toughened Polyamide 6/Polypropylene Nanocomposites
    Mat Uzir Wahit
    Azman Hassan
    Zainal Ariffin Mohd Ishak
    Abdul Razak Rahmat
    Norhayani Othman
    Polymer Journal, 2006, 38 : 767 - 780
  • [8] Nanocomposites of Polyamide 6 and Organoclay: Crystallinity and Study of Mechanical Properties
    de Oliveira, Marcelo F. L.
    de Oliveira, Marcia G.
    Leite, Marcia C. A. M.
    POLIMEROS-CIENCIA E TECNOLOGIA, 2011, 21 (01): : 78 - 82
  • [9] Epoxidized natural rubber toughened polylactic acid/talc composites: Mechanical, thermal, and morphological properties
    Akbari, Abozar
    Jawaid, M.
    Hassan, Azman
    Balakrishnan, Harintharavimal
    JOURNAL OF COMPOSITE MATERIALS, 2014, 48 (07) : 769 - 781
  • [10] Morphology and mechanical properties of PA6/organoclay nanocomposites toughened by bulk rubber and core-shell rubber
    Zhou, C.
    Teng, Y.
    Zhou, L.
    Sun, S.
    Yang, H.
    PLASTICS RUBBER AND COMPOSITES, 2015, 44 (08) : 339 - 344