Synthesis and photochemical properties of phthalocyanine zinc(II) complexes containing o-carborane units

被引：35
|
作者：
Woehrle, Dieter [1 ]
Tsaryova, Olga [1 ]
Semioshkin, Andrey [2 ]
Gabel, Detlef [1 ]
Suvorova, Olga [3 ]
机构：
[1] Univ Bremen, Fac Biol & Chem, D-28334 Bremen, Germany
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[3] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 747卷
关键词：
Phthalocyanine zinc; o-Carborane; Singlet oxygen; Photooxidation; Citronellol; NEUTRON-CAPTURE THERAPY; POLYHEDRAL BORON-COMPOUNDS; OXYGEN QUANTUM YIELDS; PHOTODYNAMIC THERAPY; PHOTOSENSITIZERS; DERIVATIVES; PHOTOOXIDATIONS; CHEMISTRY; METAL;
D O I：
10.1016/j.jorganchem.2013.03.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of novel phthalocyanine zinc(II) complexes containing o-carborane units are described. The following properties of o-carboranyl-substituted phthalocyanines were investigated: singlet oxygen quantum yield, photo-oxidative stability, photocatalytic activity in the photooxidation of (S)-(-)-citronellol. The o-carboranyl substituted phthalocyanine zinc(II) complexes exhibit improved singlet oxygen quantum yields, photo-oxidative stabilities, photocatalytic activities compared to phthalocyanine zinc(II) complexes without o-carboranyl groups. Therefore these o-carboranyl complexes are of interest for use in cancer therapy. (C) 2013 Elsevier B. V. All rights reserved.
引用
收藏
页码：98 / 105
页数：8
相关论文
共 50 条
  • [31] Tetrabutylammonium fluoride promoted synthesis of o-carborane derivatives.
    Plazas, A
    Arellanes, G
    Gomez, FA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U403 - U403
  • [32] Phosphorescence Color Tuning of Cyclometalated Iridium Complexes by o-Carborane Substitution
    Kim, Taewon
    Kim, Hyungjun
    Lee, Kang Mun
    Lee, Yoon Sup
    Lee, Min Hyung
    INORGANIC CHEMISTRY, 2013, 52 (01) : 160 - 168
  • [33] Theoretical insights into the effect of ligands on platinum(ii) complexes with a bidentate bis(o-carborane) ligand structure
    Zhao, Ancong
    Cai, Wanlin
    Yan, Xi
    Zhang, Huize
    Wang, Jian
    Shen, Wei
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2019, 18 (10) : 2421 - 2429
  • [34] Synthesis, characterization, photophysical, and photochemical properties of novel zinc(II) and indium(III) phthalocyanines containing 2-phenylphenoxy units
    Ali, Haytham Elzien Alamin
    Piskin, Mehmet
    Altun, Selcuk
    Durmus, Mahmut
    Odabas, Zafer
    JOURNAL OF LUMINESCENCE, 2016, 173 : 113 - 119
  • [35] Synthesis of quadruped-shaped polyfunctionalized o-carborane synthons
    Puga, Alberto V.
    Teixidor, Francesc
    Sillanpaa, Reijo
    Kivekas, Raikko
    Vinas, Clara
    CHEMICAL COMMUNICATIONS, 2011, 47 (08) : 2252 - 2254
  • [36] Deep Red Phosphorescence of Cyclometalated Iridium Complexes by o-Carborane Substitution
    Bae, Hye Jin
    Chung, Jin
    Kim, Hyungjun
    Park, Jihyun
    Lee, Kang Mun
    Koh, Tae-Wook
    Lee, Yoon Sup
    Yoo, Seunghyup
    Do, Youngkyu
    Lee, Min Hyung
    INORGANIC CHEMISTRY, 2014, 53 (01) : 128 - 138
  • [37] Theoretical insights into the effect of ligands on platinum(II) complexes with a bidentate bis(o-carborane) ligand structure†
    Ancong Zhao
    Wanlin Cai
    Xi Yan
    Huize Zhang
    Jian Wang
    Wei Shen
    Photochemical & Photobiological Sciences, 2019, 18 : 2421 - 2429
  • [38] Effects of substituents and solvents on the photochemical properties of zinc phthalocyanine complexes and their protonated derivatives
    Ogunsipe, A
    Nyokong, T
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 689 (1-2) : 89 - 97
  • [39] Synthesis and Photophysical/Photochemical Properties of Aryloxy Substituted Phthalocyanine Zinc Complex
    Liu Hong
    Zhang Lei
    Jia Xiao
    Liu Jian-Yong
    Xue Jin-Ping
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2013, 29 (03) : 486 - 492
  • [40] Photophysical, photochemical and BSA binding/BQ quenching properties of quaternizable coumarin containing water soluble zinc phthalocyanine complexes
    Esenpinar, Aliye Asli
    Durmus, Mahmut
    Bulut, Mustafa
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 79 (03) : 608 - 617
12345