Enhanced ferroelectric and piezoelectric response in Mn-doped Bi0.5Na0.5TiO3-BaTiO3 lead-free film by pulsed laser deposition

被引:26
作者
Jin, Chengchao [1 ]
Wang, Feifei [1 ]
Leung, Chung Ming [2 ]
Yao, Qirong [1 ]
Tang, Yanxue [1 ]
Wang, Tao [1 ]
Shi, Wangzhou [1 ]
机构
[1] Shanghai Normal Univ, Math & Sci Coll, Key Lab Optoelect Mat & Device, Shanghai 200234, Peoples R China
[2] Hong Kong Polytech Univ, Dept Elect Engn, Kowloon, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
Lead-free thin film; Pulsed laser deposition; Piezoelectric properties; Ferroelectric properties; THIN-FILMS; DOMAIN; SI; ISSUES; MEMS;
D O I
10.1016/j.apsusc.2013.06.114
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mn-doped Bi0.5Na0.5TiO3-BaTiO3 thin film with the composition around the morphotropic phase boundary was grown on Pt-electrodized Si substrate by pulsed laser deposition. Highly (1 0 0)-oriented film with pure perovskite structure was obtained through carefully controlling the growth conditions. Well-defined ferroelectric P-E loop was obtained with the average remnant polarization P-r and coercive field E-c of similar to 11.3 mu C/cm(2) and similar to 6.5 kV/mm, respectively. Polycrystalline structures and multidomain states were revealed by piezoresponse force microscopy and large local strain response was obtained with the normalized strain S-max/E-max up to 92 pm/V. The excellent global electrical properties make it quite promising in environmental-friendly ferroelectric and piezoelectric devices. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:348 / 351
页数:4
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