The promotional effect of Sn-beta zeolites on platinum for the selective hydrogenation of α,β-unsaturated aldehydes

被引：37
作者：
Concepcion, Patricia [1 ]
Perez, Yolanda [2 ]
Hernandez-Garrido, J. C. [3 ]
Fajardo, Mariano [2 ]
Calvino, J. J. [3 ]
Corma, Avelino [1 ]
机构：
[1] Univ Politecn Valencia, Inst Tecnol Quim CSIC UPV, Valencia 46022, Spain
[2] Univ Rey Juan Carlos, ESCET, Dept Quim Inorgan & Analt, Madrid 28933, Spain
[3] Univ Cadiz, Fac Ciencias, Dept Ciencia Mat Ingn Met & Quim Inorgan, Cadiz 11510, Spain
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 29期
关键词：
LIQUID-PHASE HYDROGENATION; CITRAL HYDROGENATION; UNSATURATED ALDEHYDES; ACTIVATED CARBON; CHEMOSELECTIVE HYDROGENATION; CATALYTIC-PROPERTIES; SUPPORTED CATALYSTS; CINNAMYL ALCOHOL; COPPER ADDITION; PTSN ALLOY;
D O I：
10.1039/c3cp50519g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Pt impregnated on a Sn-beta catalyst results in a very promising catalyst for the selective hydrogenation of alpha,beta-unsaturated aldehydes, compared to the PtSn co-impregnated beta catalysts. Framework tin ions in the Sn-beta sample stabilize the nucleation of platinum nanoparticles inside the zeolite channel. These Pt-0-Sn4+ sites, which are only observed in the Pt/Sn-beta catalyst, have been shown to strongly activate the carbonyl group enhancing the hydrogenation rate of the C=O bond.
引用
收藏
页码：12048 / 12055
页数：8
相关论文
共 59 条
[1]   Changes in the selective hydrogenation of citral induced by copper addition to Ru/KL catalysts [J].
Alvarez-Rodriguez, J. ;
Guerrero-Ruiz, A. ;
Rodriguez-Ramos, I. ;
Arcoya, A. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 110 (2-3) :186-196
[2]   Modifications of the citral hydrogenation selectivities over Ru/KL-zeolite catalysts induced by the metal precursors [J].
Alvarez-Rodríguez, J ;
Guerrero-Ruiz, A ;
Rodríguez-Ramos, I ;
Arcoya-Martín, A .
CATALYSIS TODAY, 2005, 107-08 :302-309
[3]   Selective hydrogenation of citral over Pt/KL type catalysts doped with Sr, La, Nd and Sm [J].
Alvarez-Rodriguez, J. ;
Rodriguez-Ramos, I. ;
Guerrero-Ruiz, A. ;
Arcoya, A. .
APPLIED CATALYSIS A-GENERAL, 2011, 401 (1-2) :56-64
[4]   Effect of nickel precursor and the copper addition on the surface properties of Ni/KL-supported catalysts for selective hydrogenation of citral [J].
Alvarez-Rodriguez, Jesus ;
Cerro-Alarcon, Miriam ;
Guerrero-Ruiz, Antonio ;
Rodriguez-Ramos, Inmaculada ;
Arcoya, Adolfo .
APPLIED CATALYSIS A-GENERAL, 2008, 348 (02) :241-250
[5]   Surface and structural effects in the hydrogenation of citral over RuCu/KL catalysts [J].
Alvarez-Rodriguez, Jesus ;
Guerrero-Ruiz, Antonio ;
Rodriguez-Ramos, Inmaculada ;
Arcoya-Martin, Adolfo .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 97 (1-3) :122-131
[6]   Surface changes in Ru/KL supported catalysts induced by the preparation method and their effect on the selective hydrogenation of citral [J].
Alvarez-Rodriguez, Jesus ;
Rodriguez-Ramos, Inmaculada ;
Guerrero-Ruiz, Antonio ;
Arcoya, Adolfo .
APPLIED CATALYSIS A-GENERAL, 2009, 366 (01) :114-121
[7]   FTIR study of CO adsorption on coked Pt-Sn/Al2O3 catalysts [J].
Arteaga, GJ ;
Anderson, JA ;
Rochester, CH .
CATALYSIS LETTERS, 1999, 58 (04) :189-194
[8]   Modification of catalytic properties over carbon supported Ru-Cu and Ni-Cu bimetallics -: I.: Functional selectivities in citral and cinnamaldehyde hydrogenation [J].
Asedegbega-Nieto, E ;
Bachiller-Baeza, B ;
Guerrero-Ruíz, A ;
Rodríguez-Ramos, I .
APPLIED CATALYSIS A-GENERAL, 2006, 300 (02) :120-129
[9]   Hydrogenation of citral on activated carbon and high-surface-area graphite-supported ruthenium catalysts modified with iron [J].
Bachiller-Baeza, B ;
Guerrero-Ruiz, A ;
Wang, P ;
Rodríguez-Ramos, I .
JOURNAL OF CATALYSIS, 2001, 204 (02) :450-459
[10]   THERMAL-DESORPTION INFRARED STUDY OF CARBON-MONOXIDE ADSORPTION BY ALUMINA-SUPPORTED PLATINUM [J].
BARTH, R ;
PITCHAI, R ;
ANDERSON, RL ;
VERYKIOS, XE .
JOURNAL OF CATALYSIS, 1989, 116 (01) :61-70
123456