Hydrogen-Bonding in Aminocatalysis: From Proline and Beyond

被引：116
|
作者：
Albrecht, Lukasz [2 ]
Jiang, Hao [1 ]
Jorgensen, Karl Anker [1 ]
机构：
[1] Aarhus Univ, Dept Chem, Ctr Catalysis, DK-8000 Aarhus C, Denmark
[2] Lodz Univ Technol, Inst Organ Chem, Dept Chem, PL-90924 Lodz, Poland
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 02期
关键词：
aminocatalysis; asymmetric catalysis; bifunctional catalysis; hydrogen bonds; proline; stereoselective synthesis; ENANTIOSELECTIVE MICHAEL ADDITION; DIRECT ALDOL REACTIONS; ASYMMETRIC ALDOL; BIFUNCTIONAL ORGANOCATALYSTS; PYRROLIDINE-THIOUREA; CONJUGATE ADDITION; CYCLIC-KETONES; ALPHA-CHLORINATION; NITRO-MICHAEL; ALDEHYDES;
D O I：
10.1002/chem.201303982
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This Concept article summarizes recent progress in the field of hydrogen-bonding aminocatalysis using proline-derived systems. The aminocatalysts available in the literature are categorized by the incorporated hydrogen- bonding scaffold and its mode of recognition. Both mono- and double-hydrogen-bonding motifs are discussed and examples of their application in asymmetric synthesis are given. © 2014 Wiley-VCH Verlag GmbH& Co.
引用
收藏
页码：358 / 368
页数：11
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