Fischer-Tropsch synthesis using zeolite-supported iron catalysts for the production of light hydrocarbons

被引：68

作者：

Kang, Suk-Hwan ^{[1
]}

Bae, Jong Wook ^{[1
]}

Prasad, P. S. Sai ^{[1
]}

Jun, Ki-Won ^{[1
]}

机构：

[1] Korea Res Inst Chem Technol, Alternat Chem Fuel Res Ctr, Taejon 305600, South Korea

来源：

CATALYSIS LETTERS | 2008年 / 125卷 / 3-4期

关键词：

Fischer-Tropsch synthesis; iron; zeolites; light hydrocarbons; acidity;

D O I：

10.1007/s10562-008-9586-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fischer-Tropsch synthesis (FTS) for the production of olefins from syngas was investigated on FeCuK impregnated on zeolite catalysts such as ZSM-5, Mordenite and Beta-zeolite. ZSM-5 supported catalyst showed the best activity among the three catalysts due to the high reducibility of iron oxides. It also exhibited high olefin selectivity compared to a catalyst prepared by physical mixing of the two components, due to the presence of moderate number of acid sites.

引用

页码：264 / 270

页数：7

共 31 条

[1]

Bartholomew C.H., 1991, STUD SURF SCI CATAL, V64, P158

[2]

BASU PK, 1991, FUEL SCI TECHNOL, V10, P91

[3] Studies with a precipitated iron Fischer-Tropsch catalyst reduced by H2 or CO [J].

Bian, GZ ;

Oonuki, A ;

Koizumi, N ;

Nomoto, H ;

Yamada, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 186 (1-2) :203-213

[4] The addition of HZSM-5 to the Fischer-Tropsch process for improved gasoline production [J].

Botes, FG ;

Böhringer, W .

APPLIED CATALYSIS A-GENERAL, 2004, 267 (1-2) :217-225

[5] SYNTHESIS GAS CONVERSION TO AROMATIC-HYDROCARBONS [J].

CHANG, CD ;

LANG, WH ;

SILVESTRI, AJ .

JOURNAL OF CATALYSIS, 1979, 56 (02) :268-273

[6] SYNTHESIS OF MOTOR FUELS FROM HY-ZEOLITE SUPPORTED FISCHER-TROPSCH IRON CATALYSTS [J].

EGIEBOR, NO ;

COOPER, WC ;

WOJCIECHOWSKI, BW .

APPLIED CATALYSIS, 1989, 55 (01) :47-64

[7] Photo-degradation of acid green dye over Co-ZSM-5 catalysts prepared by incipient wetness impregnation technique [J].

El-Bahy, Zeinhom M. ;

Mohamed, Mohamed M. ;

Zidan, Farouk I. ;

Thabet, Mohamed S. .

JOURNAL OF HAZARDOUS MATERIALS, 2008, 153 (1-2) :364-371

[8] Effect of operating conditions on the synthesis of dimethyl ether over a CuO-ZnO-Al2O3/NaHZSM-5 bifunctional catalyst [J].

Ereña, J ;

Garoña, R ;

Arandes, JM ;

Aguayo, AT ;

Bilbao, J .

CATALYSIS TODAY, 2005, 107-08 :467-473

[9]

Espinoza R.L., 2006, USP, Patent No. 07067562

[10] Development of catalysts for the production of aromatics from syngas [J].

Guan, N ;

Liu, Y ;

Zhang, M .

CATALYSIS TODAY, 1996, 30 (1-3) :207-213

← 1 2 3 4 →