A facile transesterification route to ferrocenyl esters

被引：13

作者：

Debroy, P ^{[1
]}

Naskar, D ^{[1
]}

Roy, S ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Organomet & Catalysis Lab, Kharagpur 721302, W Bengal, India

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 04期

关键词：

ferrocene; ene-linker; transesterification; tetrabutylammonium hydroxide; RCM;

D O I：

10.1016/j.ica.2005.09.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of tetrabutylammonium hydroxide as catalyst and at room temperature, ethyl ferrocenecarboxylate, ethyl ferrocenylacetate, ethyl 3-ferrocenylpropanoate, 1,1'-ferrocenyl-bis(ethyl propanoate), ethyl 3-ferrocenylpropenoate and 1,1'-ferrocenyl-bis(ethyl propenoate) undergoes facile transesterification reaction with aliphatic, benzyl and allyl alcohols to furnish the corresponding ferrocenyl esters in good to excellent yields. Ring closing metathesis of the ester Fc-1, 1'-(CH=CH-CO2CH2CH=CH2)(2) yields the corresponding closed loop ferrocenyl ester. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1215 / 1221

页数：7

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