Contribution of Multiwalled carbon nanotubes to dielectric and elastic properties in E7 nematic liquid crystal

被引:10
作者
Okutan, Mustafa [1 ]
Yesilot, Gursel [2 ]
Bolivar, Peter Haring [1 ]
机构
[1] Univ Siegen, Inst High Frequency & Quantum Elect, D-57076 Siegen, Germany
[2] Yildiz Tech Univ, Dept Math, TR-34220 Istanbul, Turkey
关键词
Liquid crystals; Multiwalled Carbon Nanotubes; Impedance Spectroscopy; Dielectric Anisotropy; Dielectric Strength; Splay Elastic Constant; Molecular Reorientation; CONSTANTS; LIGHT; DISPERSION;
D O I
10.1016/j.molliq.2022.120662
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this article, electrical parameters, and elastic constants of nematic liquid crystal (NLC) contributed multiwalled carbon nanotubes (MCN) are presented by dielectric spectroscopy method. The effects of reorientation on the nematic liquid crystal by doping of multi-walled carbon nanotubes were investi-gated to reveal. Analyzes of dielectric strength Ae'(x), absorption coefficient a, relaxation time r, dielec-tric anisotropy Ae' (V), dielectric anisotropy ratio 7, splay elastic constant K11, and cross-over angular frequency wco of MCN contribution to E7 nematic liquid crystal with DC supply voltage are presented. Reorientation of elastic dipolar liquid crystal molecules was demonstrated by reducing the positive type (p type) dielectric anisotropy value in the broadband angular frequency range with the MCN contribution to the E7 coded nematic liquid crystal. The supply voltage applied to the NLC samples was observed to have nearly Debye-type relaxation mechanism in the host E7 LC structure, tending to switch to a Debye-type relaxation mechanism by MCN doping. Dipole effects were enhanced by doping of multi -walled carbon nanotubes in the orientation of elastic NLC molecules, and the relaxation time of host E7 NLC and doped MCN/E7 NLC decreased with increasing bias voltages. Cole-Cole analysis with different supply voltages, it has been seen that it turns into a new equivalent circuit depending on the MCN contribution.(c) 2022 Elsevier B.V. All rights reserved.
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页数:12
相关论文
共 31 条
[1]   Molecular dynamics calculation of elastic constants in Gay-Berne nematic liquid crystals [J].
Allen, MP ;
Warren, MA ;
Wilson, MR ;
Sauron, A ;
Smith, W .
JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (07) :2850-2858
[2]  
[Anonymous], 1994, Electrooptic Effects in Liquid Crystal Materials
[3]   Dispersion and absorption in dielectrics I. Alternating current characteristics [J].
Cole, KS ;
Cole, RH .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351
[4]   Synthesis, characterization of V2O5 nanoparticle and dispersion of them into nematic liquid crystal [J].
Eskalen, Hasan ;
Ozgan, Sukru ;
Kerli, Suleyman .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2019, 125 (12)
[5]   ON THE THEORY OF LIQUID CRYSTALS [J].
FRANK, FC .
DISCUSSIONS OF THE FARADAY SOCIETY, 1958, (25) :19-28
[6]   Effect of titanium oxide nanoparticles on the dielectric properties and ionic conductivity of a new smectic bis-imidazolium salt with dodecyl sulfate anion and cyanobiphenyl mesogenic groups [J].
Ganea, Constantin Paul ;
Circu, Viorel ;
Manaila-Maximean, Doina .
JOURNAL OF MOLECULAR LIQUIDS, 2020, 317
[7]  
Guo Y., 2019, NANOTECHNOLOGY, V30
[8]   Effect of disubstitution pattern of the terminal alkyl chains on the mesophase of liquid crystals based on lanthanide(III) complexes: A study of the thermal, emission and dielectric behavior [J].
Ilinca, Theodora A. ;
Chiriac, Laura F. ;
Ilis, Monica ;
Manaila-Maximean, Doina ;
Ganea, Paul C. ;
Pasuk, Iuliana ;
Circu, Viorel .
JOURNAL OF MOLECULAR LIQUIDS, 2022, 360
[9]   Optical characterization of a dual-frequency hybrid aligned nematic liquid crystal cell [J].
Jewell, SA ;
Sambles, JR .
OPTICS EXPRESS, 2005, 13 (07) :2627-2633
[10]  
Jonscher AK., 1983, Dielectric relaxation in solids