Physical ageing in poly(ethylene terephthalate) - its influence on cold crystallisation

被引:30
作者
McGonigle, EA
Daly, JH
Gallagher, S
Jenkins, SD
Liggat, JJ
Olsson, I
Pethrick, RA
机构
[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[2] Dupont Polyester, Wilton Res Ctr, Middlesbrough TS90 8JE, Cleveland, England
基金
英国工程与自然科学研究理事会;
关键词
poly(ethylene terephthalate); physical ageing; cold crystallisation;
D O I
10.1016/S0032-3861(99)00015-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The relationship between the crystallisation behaviour and physical ageing history of poly(ethylene terephthalate) is reported. It is shown that short term ageing can enhance the subsequent rate of crystallisation, but longer ageing times can retard the crystallisation process. It is suggested that physical ageing favours the formation of ordered domains. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4977 / 4982
页数:6
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