Upside Down! Crystallographic and Spectroscopic Characterization of an [FeIV(Osyn)(TMC)2+ Complex

被引：26

作者：

Prakash, Jai ^{[1
,2
]}

Rohde, Gregory T. ^{[1
,2
]}

Meier, Katlyn K. ^{[3
]}

Muenck, Eckard ^{[3
]}

Que, Lawrence, Jr. ^{[1
,2
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA

[3] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 23期

基金：

美国国家科学基金会;

关键词：

FE-IV=O COMPLEXES; OXOIRON(IV) COMPLEX; CYCLAM LIGANDS; REACTIVITY; BEARING;

D O I：

10.1021/acs.inorgchem.5b02011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fe-II(TMC)(OTf)(2) reacts with 2-(BuSO2)-Bu-t-C6H4IO to afford an oxoiron(IV) product, 2, distinct from the previously reported [Fe-IV(O-anti) (TMC) (NCMe)](2+). In MeCN, 2 has a blue-shifted near-IR band, a higher nu(Fe=O), a larger Mossbauer quadrupole splitting, and quite a distinct H-1 NMR spectrum. Structural analysis of crystals grown from CH2Cl2 reveals a complex with the formulation of [Fe-IV(O)(TMC)(OTf)](OTf) and the shortest Fe-IV=O bond 1.625(4) angstrom] found to date.

引用

页码：11055 / 11057

页数：3

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