Probing orbital symmetry in solution: polarization-dependent resonant inelastic soft x-ray scattering on liquid micro-jet

被引：15

作者：

Dierker, B. ^{[1
]}

Suljoti, E. ^{[1
]}

Atak, K. ^{[1
,2
]}

Lange, K. M. ^{[1
]}

Engel, N. ^{[1
,2
]}

Golnak, R. ^{[1
,2
]}

Dantz, M. ^{[1
]}

Hodeck, K. ^{[1
]}

Khan, M. ^{[2
]}

Kosugi, N. ^{[3
]}

Aziz, E. F. ^{[1
,2
]}

机构：

[1] Helmholtz Zentrum Berlin Mat & Energie, Joint Ultrafast Dynam Lab Solut & Interfaces JULi, D-12489 Berlin, Germany

[2] Free Univ Berlin, D-14195 Berlin, Germany

[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

NEW JOURNAL OF PHYSICS | 2013年 / 15卷

基金：

欧洲研究理事会;

关键词：

ELECTRON-ENERGY-LOSS; SPECTROSCOPY; EMISSION; INNER; EXCITATION; ANISOTROPY; MOLECULES; BOND;

D O I：

10.1088/1367-2630/15/9/093025

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Polarization-dependent resonant inelastic x-ray scattering is demonstrated here for liquid acetonitrile, acetone and dimethyl sulfoxide, using the liquid micro-jet technique. Selective excitation to an unoccupied orbital with a specific symmetry at the K-edge x-ray absorption of liquid samples determines the polarization-dependent emission of the occupied states. Considering the well-defined unoccupied molecular orbital configuration and utilizing the results of ab initio molecular orbital calculations, the polarization-dependent anisotropy in resonant inelastic soft x-ray scattering is discussed in a membrane-free configuration.

引用

页数：10

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