Organic-inorganic hybrids containing phosphonate groups obtained by sol-gel process

被引:0
作者
Ilia, G. [1 ,2 ]
Parvulescu, V. [3 ]
Popa, A. [1 ]
Iliescu, S. [1 ]
机构
[1] Inst Chem Timisoara, Timisoara 300223, Romania
[2] West Univ, Fac Chem Biol & Goeg, Timisoara 300115, Romania
[3] Inst Phys Chem IG Murgulescu, Bucharest 060021, Romania
来源
JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS | 2008年 / 10卷 / 12期
关键词
Organic-inorganic hybrids; Sol-gel; Phosphonates;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Organophosphorus acids and their derivatives are highly promising coupling molecules that allow the anchoring of organic groups to inorganic solids. In this paper we present the synthesis, by sol-gel method, of organic-inorganic hybrids containing organic phosphonic groups. The obtained hybrid materials were characterized by N(2) adsorption/desorption, IR Spectroscopy, Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). IR spectra of the obtained samples show in the 900-1300 region the presence of the vibration typical of phosphonates group. These results suggest the formation of the hybrid network containing Si-O-Si and Si-O-P bonds. TEM, SEM micrographs show mezzo-macroporous materials with high surface area. A low ordered mesoporous structure was evidenced by TEM images.
引用
收藏
页码:3398 / 3402
页数:5
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