Polypyrrole@metal-organic framework (UIO-66)@cotton fabric electrodes for flexible supercapacitors

被引：77
作者：
Zhang, Chuanjie [1 ]
Tian, Jiaxin [1 ]
Rao, Weida [1 ]
Guo, Bin [2 ]
Fan, Lingling [3 ]
Xu, Weilin [1 ]
Xu, Jie [1 ]
机构：
[1] Wuhan Text Univ, State Key Lab Hubei New Text Mat & Adv Proc Techn, Hubei Key Lab Biomass Fibers & Ecodyeing & Finish, Coll Mat Sci & Engn, Wuhan 430200, Hubei, Peoples R China
[2] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Jiangsu, Peoples R China
[3] Wuhan Text Univ, Coll Text Sci & Engn, Wuhan 430200, Hubei, Peoples R China
来源：
CELLULOSE | 2019年 / 26卷 / 05期
关键词：
Metal-organic frameworks; Polypyrrole; Fabric electrodes; Flexible supercapacitors; NANOFIBROUS COMPOSITE MEMBRANES; SOLID-STATE SUPERCAPACITOR; COATED COTTON FABRICS; ENERGY-STORAGE; FACILE SYNTHESIS; SILVER NANOPARTICLES; CONDUCTING POLYMERS; SMART; NANOTUBES; TEXTILE;
D O I：
10.1007/s10570-019-02321-3
中图分类号：
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号：
0805 ; 080502 ; 0822 ;
摘要：
Metal-organic frameworks (MOFs) are recently attracting more and more interests as supercapacitor electrode materials. However, their low conductivity largely thwarts their capacitance performance. Herein, fabric electrodes for flexible supercapacitors were successfully fabricated by depositing polypyrrole (PPy) nanotubes and Zr-based MOF (UiO-66) particles on cotton fabrics. The PPy nanotubes could serve as conductive connectors to bridge the UIO-66 particles due to their superior conductivity with one-dimensional structure. The conductivity of the PPy@UIO-66@cotton fabric electrode was increased to 14.29Scm(-1). A specific capacitance of 565Fg(-1) at a current density of 0.8mAcm(-2) was obtained for the PPy@UIO-66@cotton fabric electrode. In addition, the proposed fabric electrode exhibited good cycling stability with capacitance retention of 90% after 500 charge-discharge cycles and excellent rate capability. This study confirmed the combination of MOFs and PPy nanotubes has great application prospect in fabric-based flexible supercapacitors.
引用
收藏
页码：3387 / 3399
页数：13
相关论文
共 64 条
[1]   Effects of ammonium hydroxide on the structure and gas adsorption of nanosized Zr-MOFs (UiO-66) [J].
Abid, Hussein Rasool ;
Ang, Ha Ming ;
Wang, Shaobin .
NANOSCALE, 2012, 4 (10) :3089-3094
[2]   The composites of silver with globular or nanotubular polypyrrole: The control of silver content [J].
Alekseeva, Elizaveta ;
Bober, Patrycja ;
Trchova, Miroslava ;
Sedenkova, Ivana ;
Prokes, Jan ;
Stejskal, Jaroslav .
SYNTHETIC METALS, 2015, 209 :105-111
[3]   Towards seamlessly-integrated textile electronics: methods to coat fabrics and fibers with conducting polymers for electronic applications [J].
Allison, Linden ;
Hoxie, Steven ;
Andrew, Trisha L. .
CHEMICAL COMMUNICATIONS, 2017, 53 (53) :7182-7193
[4]   Facile synthesis of flexible electrode based on cotton/polypyrrole/multi-walled carbon nanotube composite for supercapacitors [J].
Bo, Yang ;
Zhao, Yaping ;
Cai, Zaisheng ;
Bahi, Addie ;
Liu, Caihong ;
Ko, Frank .
CELLULOSE, 2018, 25 (07) :4079-4091
[5]   Supercapacitors of Nanocrystalline Metal-Organic Frameworks [J].
Choi, Kyung Min ;
Jeong, Hyung Mo ;
Park, Jung Hyo ;
Zhang, Yue-Biao ;
Kang, Jeung Ku ;
Yaghi, Omar M. .
ACS NANO, 2014, 8 (07) :7451-7457
[6]   Surface assembly of nano-metal organic framework on amine functionalized indium tin oxide substrate for impedimetric sensing of parathion [J].
Deep, Akash ;
Bhardwaj, Sanjeev Kumar ;
Paul, A. K. ;
Kim, Ki-Hyun ;
Kumar, Pawan .
BIOSENSORS & BIOELECTRONICS, 2015, 65 :226-231
[7]   Increase in Electrical Conductivity of MOF to Billion-Fold upon Filling the Nanochannels with Conducting Polymer [J].
Dhara, Barun ;
Nagarkar, Sanjog S. ;
Kumar, Jitender ;
Kumar, Vikash ;
Jha, Plawan Kumar ;
Ghosh, Sujit K. ;
Nair, Sunil ;
Ballav, Nirmalya .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (15) :2945-2950
[8]   Towards flexible solid-state supercapacitors for smart and wearable electronics [J].
Dubal, Deepak P. ;
Chodankar, Nilesh R. ;
Kim, Do-Heyoung ;
Gomez-Romero, Pedro .
CHEMICAL SOCIETY REVIEWS, 2018, 47 (06) :2065-2129
[9]   Idealized powder diffraction patterns for cellulose polymorphs [J].
French, Alfred D. .
CELLULOSE, 2014, 21 (02) :885-896
[10]   Flexible solid-state supercapacitor of metal-organic framework coated on carbon nanotube film interconnected by electrochemically - codeposited PEDOT-GO [J].
Fu, Dongying ;
Zhou, Haihan ;
Zhang, Xian-Ming ;
Han, Gaoyi ;
Chang, Yunzhen ;
Li, Haowen .
CHEMISTRYSELECT, 2016, 1 (02) :285-289
1234567