Tartrate-based ionic liquids: unified synthesis and characterisation

被引：11

作者：

Rouch, Anne ^{[1
]}

Castellan, Tessa ^{[1
]}

Fabing, Isabelle ^{[1
]}

Saffon, Nathalie ^{[2
]}

Rodriguez, Jean ^{[3
]}

Constantieux, Thierry ^{[3
]}

Plaquevent, Jean-Christophe ^{[1
]}

Genisson, Yves ^{[1
]}

机构：

[1] Univ Toulouse 3, CNRS, LSPCMIB, UMR 5068, F-31062 Toulouse, France

[2] Univ Toulouse 3, ICT FR 2599, Inst Chim Toulouse, F-31062 Toulouse, France

[3] Aix Marseille Univ, CNRS, ISm2, UMR 7313, F-13397 Marseille 20, France

来源：

RSC ADVANCES | 2013年 / 3卷 / 02期

关键词：

MULTICOMPONENT REACTIONS; SOLVENTS; CATALYSIS; WATER; EFFICIENT; SALTS;

D O I：

10.1039/c2ra21637j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient and general preparative approach for tartrate-derived organic salts with bulky non-coordinating cations is described. This route is based on neutralisation of tartaric acid with cation hydroxides in aqueous solution. A series of 24 tartrate salts was prepared by systematic variation of the hemi- or bis-tartrate anion and the nature of the organic cation. Chirality of the anion was also explored as a vector for structural modification. Complete characterisation, including X-ray crystallography, was carried out. This comparative study of the physicochemical properties of these salts led to the identification of several informative trends useful for designing proper tartrate-based chiral ionic liquids.

引用

页码：413 / 426

页数：14

共 58 条

[1] Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis-Hillman reaction
Aggarwal, VK
Emme, I
Mereu, A
[J]. CHEMICAL COMMUNICATIONS, 2002, (15) : 1612 - 1613
[2] A general halide-to-anion switch for imidazolium-based ionic liquids and oligocationic systems using anion exchange resins (A- form)
Alcalde, Ermitas
Dinares, Immaculada
Ibanez, Anna
Mesquida, Neus
[J]. CHEMICAL COMMUNICATIONS, 2011, 47 (11) : 3266 - 3268
[3] Facile synthesis of ionic liquids possessing chiral carboxylates
Allen, Christine R.
Richard, Paulina L.
Ward, Antony J.
van de Water, Leon G. A.
Masters, Anthony F.
Maschmeyer, Thomas
[J]. TETRAHEDRON LETTERS, 2006, 47 (41) : 7367 - 7370
[4] Characterizing ionic liquids on the basis of multiple solvation interactions
Anderson, JL
Ding, J
Welton, T
Armstrong, DW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) : 14247 - 14254
[5] [Anonymous], SADABS PROGR DAT COR
[6] [Anonymous], SAINT NT
[7] Capillary electrophoresis monitoring of halide impurities in ionic liquids
Berthier, D
Varenne, A
Gareil, P
Digne, M
Lienemann, CP
Magna, L
Olivier-Bourbigou, H
[J]. ANALYST, 2004, 129 (12) : 1257 - 1261
[8] Applications of chiral ionic liquids
Bica, Katharina
Gaertner, Peter
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (19) : 3235 - 3250
[9] Influence of Chiral Ionic Liquids on Stereoselective Fluorescence Quenching by Photoinduced Electron Transfer in a Naproxen Dyad
Bose, Sayantan
Wijeratne, Aruna B.
Thite, Aniket
Kraus, George A.
Armstrong, Daniel W.
Petrich, Jacob W.
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (31) : 10825 - 10829
[10] On Catalysis by Ionic Liquids
Chakraborti, Asit K.
Roy, Sudipta Raha
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) : 6902 - +

← 1 2 3 4 5 6 →