Visible-Light-Promoted C-C Bond Cleavage: Photocatalytic Generation of Iminium Ions and Amino Radicals

被引：129

作者：

Cai, Shunyou ^{[1
]}

Zhao, Xinyang ^{[1
]}

Wang, Xinbo ^{[1
]}

Liu, Qisong ^{[1
]}

Li, Zigang ^{[1
]}

Wang, David Zhigang ^{[1
]}

机构：

[1] Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Key Lab Chem Genom, Shenzhen 518055, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 32期

基金：

中国国家自然科学基金;

关键词：

amines; C-C activation; photochemistry; radicals; ruthenium; PHOTOREDOX CATALYSIS; H FUNCTIONALIZATION; POLYMERIZATION REACTIONS; CYCLOADDITIONS; ORGANOCATALYSIS; ALDEHYDES; STRATEGY; TRIFLUOROMETHYLATION; CONSTRUCT; HALIDES;

D O I：

10.1002/anie.201202880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8050 / 8053

页数：4

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