Polymeric Salphen-Phthalocyanine Dinuclear Metal Complexes for Activation of Molecular Oxygen

被引：10

作者：

Wang, Rong-Min ^{[1
]}

Hao, Er-Xia ^{[1
]}

Shen, Guo-Rui ^{[1
]}

He, Yu-Feng ^{[1
]}

Lei, Zi-Qiang ^{[1
]}

机构：

[1] NW Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Lanzhou 730070, Peoples R China

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2009年 / 111卷 / 04期

基金：

芬兰科学院; 中国国家自然科学基金;

关键词：

polymeric dinuclear metal complex; polyphthalocyanines; salphen schiff base metal complexes; sheet polymer; molecular oxygen; catalytic oxidation; SALEN-CROWN ETHER; COPPER PHTHALOCYANINE; CATALYTIC ACTIVATION; AEROBIC OXIDATION; PHOTOCONDUCTIVITY; DECOMPOSITION; HYDROXYLATION; EPOXIDATION; COPOLYMER; BEHAVIOR;

D O I：

10.1002/app.29277

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymeric Salphen Schiff base-phthalocyanine Co-Cu dinuclear metal complex (PSalphenCo-PcCu) was designed and synthesized through interfacial condensation polymerization. The new sheet polymeric dinuclear metal complex has been characterized by IR spectra, UV-visible spectra, scanning electron microscopy with energy dispersive X-ray analysis and thermogravimetry analysis. Its catalytic activity for activation of molecular oxygen was investigated by using cumene as substrate without any additive in mild condition. The aerobic oxidation of cumene catalyzed by PSalphenCo-PcCu, proved to be a simple and efficient method for obtaining cumene hydroperoxide in a high selectivity. (c) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 1999-2005, 2009

引用

页码：1999 / 2005

页数：7

共 29 条

[1] Studies on phthalocyanine sheet polymers [J].