Tris(triorganosilyl)methyl derivatives of potassium and lithium bearing dimethylamino or methoxy substituents at silicon.: Crystal structures of KC(SiMe3)2(SiMe2NMe2), KC(SiMe2NMe2)3 and [LiC(SiMe3)(SiMe2OMe)2]2

被引：22
作者：
Al-Juaid, SS
Eaborn, C [1 ]
El-Hamruni, S
Farook, A
Hitchcock, PB
Hopman, M
Smith, JD
Clegg, W
Izod, K
O'Shaughnessy, P
机构：
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
[2] Newcastle Univ, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 18期
关键词：
D O I：
10.1039/a904043i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds HC(SiMe3)(SiMe2X)(2), X = NMe2 or OMe, have been synthesized in several steps from the phenyl derivative HC(SiMe3)(SiMe2Ph)(2) and metallated to give organometallic compounds of the type MC(SiMe3)(SiMe2X)(2), M = K or Li. The structures of the compounds KC(SiMe3)(2)(SiMe2NMe2) and KC(SiMe2NMe2)(3) consist of infinite chains in which cations are co-ordinated to both nitrogen and carbon centres, whereas the lithium compound [LiC(SiMe3)(SiMe2OMe)(2)](2) crystallises in a lattice of dimeric cage molecules. Structural trends in the series MC(SiMe3)(n)(SiMe2X)(3-n), n = 0-3, M = K or Li, X = NMe2 or OMe, are discussed.
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页码：3267 / 3273
页数：7
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[1]   The novel linear-polymeric organolithium compound {(Me(2)NMe(2)Si)(3)CLi}(infinity) [J].
Adam, F ;
Eaborn, C ;
Hitchcock, PB ;
Smith, JD .
CHEMICAL COMMUNICATIONS, 1996, (06) :741-742
[2]   COMPARISON OF THE REACTIVITIES OF THE COMPOUNDS (ME3SI)2C(SIME2OME)-(SIME2CL) AND (MEOME2SI)3C(SIME2CL) - CRYSTAL-STRUCTURE OF (MEOME2SI)3-CSIPH2H [J].
AIGBIRHIO, FI ;
ALJUAID, SS ;
EABORN, C ;
HITCHCOCK, PB ;
LICKISS, PD .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1991, (09) :1407-1410
[3]   SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF THE DIMERIC ORGANOLITHIUM COMPOUND [([(MEO)ME2SI]3CLI)2] [J].
AIGBIRHIO, FI ;
BUTTRUS, NH ;
EABORN, C ;
GUPTA, SH ;
HITCHCOCK, PB ;
SMITH, JD ;
SULLIVAN, AC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (06) :1015-1018
[4]   IMPROVEMENTS IN THE PREPARATION AND USE OF "[TRIS(TRIMETHYLSILYL)METHYL]LITHIUM [J].
AIUBE, ZH ;
EABORN, C .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 269 (03) :217-218
[5]   Attachment of the new bulky ligand (Me3Si)2(Me2NMe2Si)C to Li, Hg, Al, Ga, and Sn.: Crystal structures of [Li{C(SiMe3)2(SiMe2NMe2)}(THF)2], [Hg{C(SiMe3)2(SiMe2NMe2)}2], [Al{C(SiMe3)2(SiMe2NMe2)}X2] (X = Cl, Ph), and [Ga{C(SiMe3)2(SiMe2NMe2)}Cl2] [J].
Al-Juaid, SS ;
Eaborn, C ;
El-Hamruni, SM ;
Hitchcock, PB ;
Smith, JD .
ORGANOMETALLICS, 1999, 18 (01) :45-52
[6]   METALATION OF TRIS(TRIMETHYLSILYL)METHANE AND TRIS(DIMETHYLPHENYLSILYL)METHANE WITH METHYLSODIUM - THE FIRST DIALKYLSODATE [J].
ALJUAID, SS ;
EABORN, C ;
HITCHCOCK, PB ;
IZOD, K ;
MALLIEN, M ;
SMITH, JD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (12) :1268-1270
[7]   An alkyllithium compound with a free planar carbanion.: The crystal structure of [Li(THF)4][C(SiMe2C6H4Me-o)3] [J].
Almansour, AI ;
Eaborn, C ;
Hawkes, SA ;
Hitchcock, PB ;
Smith, JD .
ORGANOMETALLICS, 1997, 16 (26) :6035-6037
[8]  
ANDIANARISON MM, 1998, J CHEM SOC DA, P249
[9]  
Armstrong DR, 1996, POLYHEDRON, V15, P3533
[10]   ELECTRON-DIFFRACTION STUDIES OF TETRAMETHYLSILANE AND HEXAMETHYLDISILANE, AND DISCUSSION OF LENGTHS OF SI-C BONDS [J].
BEAGLEY, B ;
MONAGHAN, JJ ;
HEWITT, TG .
JOURNAL OF MOLECULAR STRUCTURE, 1971, 8 (04) :401-&
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