An active and coke-resistant dry reforming catalyst comprising nickel-tungsten alloy nanoparticles

被引：44

作者：

Zhang, Shaohua ^{[1
]}

Shi, Chuan ^{[1
]}

Chen, Bingbing ^{[1
]}

Zhang, Yali ^{[1
]}

Qiu, Jieshan ^{[1
]}

机构：

[1] Dalian Univ Technol, Lab Plasma Phys Chem, Dalian, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 69卷

基金：

中国国家自然科学基金;

关键词：

Methane; Carbon dioxide; Tungsten carbide; Nickel; CARBON-DIOXIDE; SYNTHESIS GAS; METHANE; DECOMPOSITION; MOLYBDENUM; DEPOSITION; CONVERSION;

D O I：

10.1016/j.catcom.2015.06.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel catalysts catalyzing the DRM reaction have the problems of sintering and coking. Herein we proposed an idea of stabilizing nickel by Ni17W3 alloy, and alpha-WC formed during the DRM reaction participated in the CO2 activation, leading to a better coke resistance of Ni17W3/SiO2 catalyst. Due to better Ni dispersion and less coke deposition, Ni17W3/SiO2 catalyst exhibits an improved catalytic stability for the DRM reaction compared with the model Ni/SiO2 catalyst. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：123 / 128

页数：6

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