Reaction of selenium dichloride with acrylic acid and its derivatives. Regioselective synthesis of new functionalized selenides

被引：5

作者：

Potapov, V. A. ^{[1
]}

Khabibulina, A. G. ^{[1
]}

Albanov, A. I. ^{[1
]}

Amosova, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Favorskii Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 49卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

DIVINYL SULFONE; DIBROMIDE; 5-BROMO-2-BROMOMETHYL-1,3-THIASELENOLANE; TELLURIDE; SULFIDE;

D O I：

10.1134/S1070428013030044

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selenium dichloride reacted with acrylic acid, ethyl acrylate, and acrylonitrile at -20A degrees C in a regionselective fashion to give the corresponding anti-Markovnikov adducts. This reaction was used as a basis to develop an efficient procedure for the synthesis of new functionalized selenides in nearly quantitative yields. Raising the temperature to -10A degrees C or ambient led to loss of regioselectivity and formation of mixtures of addition products at both alpha- and beta-positions of the double bond.

引用

页码：342 / 344

页数：3

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