Snowman-like silver alkynyl cluster consolidated by templating chloride and peripheral trifluoroacetates

被引:72
作者
Bian, Shu-Dan [1 ]
Wang, Quan-Ming [1 ]
机构
[1] Coll Chem & Chem Engn, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
关键词
D O I
10.1039/b812451e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel nonadecanuclear silver double cage was isolated, in which a square antiprism and a pentacapped pentagonal prism templated by a chloride ion share a tetragonal face to form a snowman-like cluster that is held together by bridging alkynyl groups and trifluoroacetates.
引用
收藏
页码:5586 / 5588
页数:3
相关论文
共 18 条
[1]   Synthesis and structural characterization of a halide-free rhombohedral silver-alkynyl cage complex [Ag14(C2tBu)12][BF4]2 [J].
Abu-Salah, Omar M. ;
Ja'far, Mohammed H. ;
Al-Ohaly, Abdel Razzak ;
Al-Farhan, Khalid A. ;
Al-Enzi, Hamda S. ;
Dolomanov, Oleg V. ;
Howard, Judith A. K. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (12) :2353-2356
[2]   EXPANDING ROLES FOR TEMPLATES IN SYNTHESIS [J].
ANDERSON, S ;
ANDERSON, HL ;
SANDERS, JKM .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (09) :469-475
[3]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[4]  
2-G
[5]  
Emsley, 1989, ELEMENTS, P174
[6]   Anion receptor chemistry: highlights from 1999 [J].
Gale, PA .
COORDINATION CHEMISTRY REVIEWS, 2001, 213 :79-128
[7]   Anion coordination and anion-directed assembly: highlights from 1997 and 1998 [J].
Gale, PA .
COORDINATION CHEMISTRY REVIEWS, 2000, 199 :181-233
[8]   A 2D honeycomb-shaped network based on a starburst cluster:: [Ag4(μ3-Cl)(PPh2(CH2)2PPh2)1.5{S2P(OR)2}3] (R = Et, Pri) [J].
Liu, CW ;
Liaw, BJ ;
Liou, LS ;
Wang, JC .
CHEMICAL COMMUNICATIONS, 2005, (15) :1983-1985
[9]  
Moyer BA, 1997, SUPRAMOLECULAR CHEMISTRY OF ANIONS, P1
[10]   Directing role of anions in the syntheses of the silver-alkynyl cages [Ag14(C=CtBu)12X][BF4] (X = FCl, Br) and silver-alkynyl polymers [Ag3(C=CtBu)2(X)]n (X = Tos, NO3) [J].
Rais, D ;
Mingos, DMP ;
Vilar, R ;
White, AJP ;
Williams, DJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 652 (1-2) :87-93