The construction of two lanthanide coordination polymers based on 5-hydroxyisophthalate and bipyridine

被引：8

作者：

Zhang, Fen ^{[1
]}

Huang, Xiao-Ting ^{[1
]}

Tian, Yuan-Yuan ^{[1
]}

Gong, Ying-Xin ^{[1
]}

Chen, Xue-Yun ^{[1
]}

Lin, Jing-Jun ^{[1
]}

Lu, Dong-Sheng ^{[1
]}

Zhang, Yan-Lin ^{[1
]}

Zeng, Rong-Hua ^{[1
]}

Zheng, Sheng-Run ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou, Guangdong, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 15期

关键词：

Coordination polymers; 5-hydroxyisophthalic acid; Bipyridine; SINGLE-CRYSTAL TRANSFORMATION; LN-AG LN; ORGANIC FRAMEWORKS; LIGANDS; DESIGN; SERIES; MOLECULES; SM(III); CU(II); DONOR;

D O I：

10.1080/00958972.2013.811494

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two lanthanide coordination polymers, [Tm-2(5-IPA)(4)(2,2-Hbipy)(2)]<bold>3</bold>H2O (1, 5-H(2)IPA=5-hydroxyisophthalic acid, 2,2-bipy=2,2-bipyridine) and [Er(5-HIPA)(3)(4,4-bipy)(3)(H2O)(2)]<bold>3</bold>H2O (2, 4,4-bipy=4,4-bipyridine), have formed by hydrothermal synthesis. Complex 1 exhibits a 2-D coordination network containing parallelepiped-shaped voids occupied by guest 22-bipy molecules. Complex 2 possesses a 1-D linear chain structure. The 1-D chains are linked by 4,4-bipy molecules to form a 3-D supramolecular framework. IR spectroscopy, elemental analysis, and thermogravimetric analysis were also investigated.

引用

页码：2659 / 2668

页数：10

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