The construction of two lanthanide coordination polymers based on 5-hydroxyisophthalate and bipyridine

被引：8

作者：

Zhang, Fen ^{[1
]}

Huang, Xiao-Ting ^{[1
]}

Tian, Yuan-Yuan ^{[1
]}

Gong, Ying-Xin ^{[1
]}

Chen, Xue-Yun ^{[1
]}

Lin, Jing-Jun ^{[1
]}

Lu, Dong-Sheng ^{[1
]}

Zhang, Yan-Lin ^{[1
]}

Zeng, Rong-Hua ^{[1
]}

Zheng, Sheng-Run ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou, Guangdong, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 15期

关键词：

Coordination polymers; 5-hydroxyisophthalic acid; Bipyridine; SINGLE-CRYSTAL TRANSFORMATION; LN-AG LN; ORGANIC FRAMEWORKS; LIGANDS; DESIGN; SERIES; MOLECULES; SM(III); CU(II); DONOR;

D O I：

10.1080/00958972.2013.811494

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two lanthanide coordination polymers, [Tm-2(5-IPA)(4)(2,2-Hbipy)(2)]<bold>3</bold>H2O (1, 5-H(2)IPA=5-hydroxyisophthalic acid, 2,2-bipy=2,2-bipyridine) and [Er(5-HIPA)(3)(4,4-bipy)(3)(H2O)(2)]<bold>3</bold>H2O (2, 4,4-bipy=4,4-bipyridine), have formed by hydrothermal synthesis. Complex 1 exhibits a 2-D coordination network containing parallelepiped-shaped voids occupied by guest 22-bipy molecules. Complex 2 possesses a 1-D linear chain structure. The 1-D chains are linked by 4,4-bipy molecules to form a 3-D supramolecular framework. IR spectroscopy, elemental analysis, and thermogravimetric analysis were also investigated.

引用

页码：2659 / 2668

页数：10

共 44 条

[1]

Bruker, 2004, SMART SAINT

[2] Lanthanide-containing molecular and supramolecular polymetallic functional assemblies [J].

Bünzli, JCG ;

Piguet, C .

CHEMICAL REVIEWS, 2002, 102 (06) :1897-1928

[3] In Situ Obtained Cu(II) Compound with Coexistence of Polycatenation and Polythreading [J].

Cao, Xin-Yi ;

Lin, Qi-Pu ;

Qin, Ye-Yan ;

Zhang, Jian ;

Li, Zhao-Ji ;

Cheng, Jian-Kai ;

Yao, Yuan-Gen .

CRYSTAL GROWTH & DESIGN, 2009, 9 (01) :20-23

[4] Self-assembly of two 3D microPorous coordination polymers based on 2-oxynicotinate and oxalate ligands [J].

Chen, Hao-Zhao ;

Rong, Jian-Xiong ;

Lin, Jing-Jun ;

Cai, Xia ;

Cai, Song-Liang ;

Zeng, Rong-Hua ;

Zheng, Sheng-Run .

INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 21 :178-181

[5] Adjusting the structures of lanthanide(III) complexes by variation of the metal sources: From a 2D (32.4)(34.43.52.65.7) layer to an unusual 3D (412.63)(49.66) nia network [J].

Chen, Min ;

Wang, Cong ;

Hu, Min ;

Liu, Chun-Sen .

INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 17 :104-107

[6] Single crystal-to-single crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer [J].

Cheng, Xiao-Ning ;

Zhang, Wei-Xiong ;

Chen, Xiao-Ming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :15738-+

[7] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[8] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[9] Polytypism, homochirality, interpenetration, and hydrogen-bonding in transition metal (Mn(II), Ni(II), Cu(II), Zn(II)) 5-hydroxyisophthalate coordination polymers containing 4,4′-bipyridyl [J].

Feller, Russell K. ;

Cheetham, Anthony K. .

DALTON TRANSACTIONS, 2008, (15) :2034-2042

[10] Structural and chemical complexity in multicomponent inorganic-organic framework materials [J].

Feller, Russell K. ;

Cheetham, Anthony K. .

CRYSTENGCOMM, 2009, 11 (06) :980-985

← 1 2 3 4 5 →