Synthesis, Crystal Structure and Fluorescent Properties of Silver and Cadmium Complexes(1)

被引：0

作者：

Wang Qing-Wei ^{[1
]}

Liu Bo ^{[1
]}

Sui Wei ^{[1
]}

机构：

[1] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Dept Chem, Siping 136000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 03期

关键词：

hydrothermal synthesis; crystal structure; Ag(I) complex; Cd(II) complex; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMER; THEORETICAL CALCULATIONS; BIS(IMIDAZOL) LIGANDS; ACID; MOLECULES;

D O I：

10.14102/j.cnki.0254-5861.2011-1758

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new complexes [Ag(bix)](n)center dot nNAA center dot nH(2)O (1) and [Cd(NAA)(phen)(2)(H2O)](2)center dot 2CH(3)COO-center dot H2O (2) (bix = 1,4-bis(imidazol-1-ylmethyl)benzene, HNAA = alpha-naphthylacetic acid, phen = 1,10-phenanthroline) have been successfully synthesized under hydrothermal conditions. Their structures have been determined by elemental analyses, IR spectroscopy, TG and single-crystal X-ray diffraction analysis. The intermolecular hydrogen bonding or pi-pi stacking interactions extend the complexes into a 3D supramolecular structure. Moreover, the luminescent properties of complex 2 have been investigated in the solid state.

引用

页码：453 / 460

页数：8

共 19 条

[1] Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4'-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands [J].