First Example of a Lipophilic Porphyrin-Cardanol Hybrid Embedded in a Cardanol-Based Micellar Nanodispersion

被引：24

作者：

Bloise, Ermelinda ^{[1
]}

Carbone, Luigi ^{[2
]}

Colafemmina, Giuseppe ^{[3
]}

D'Accolti, Lucia ^{[3
]}

Mazzetto, Selma Elaine ^{[4
]}

Vasapollo, Giuseppe ^{[1
]}

Mele, Giuseppe ^{[1
]}

机构：

[1] Univ Salento, Dept Engn Innovat, I-73100 Lecce, Italy

[2] CNR, Inst Nanosci, NNL, I-73100 Lecce, Italy

[3] Univ Bari A Moro, Dept Chem, I-70126 Bari, Italy

[4] Univ Fed Ceara, Lab Prod & Proc Technol LPT, Dept Organ & Inorgan Chem, BR-6021 Fortaleza, Ceara, Brazil

来源：

MOLECULES | 2012年 / 17卷 / 10期

关键词：

cardanol; cholesterol; lipophilic porphyrin; cardanol hybrid; micellar dispersion; SHELL LIQUID CNSL; PHOTOCATALYTIC DEGRADATION; SELF-DIFFUSION; 4-NITROPHENOL; PHOTODEGRADATION;

D O I：

10.3390/molecules171012252

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Cardanol is a natural and renewable organic raw material obtained as the major chemical component by vacuum distillation of cashew nut shell liquid. In this work a new sustainable procedure for producing cardanol-based micellar nanodispersions having an embedded lipophilic porphyrin itself peripherally functionalized with cardanol substituents (porphyrin-cardanol hybrid) has been described for the first time. In particular, cardanol acts as the solvent of the cardanol hybrid porphyrin and cholesterol as well as being the main component of the nanodispersions. In this way a "green" micellar nanodispersion, in which a high percentage of the micellar system is derived from renewable "functional" molecules, has been produced.

引用

页码：12252 / 12261

页数：10

共 32 条

[11] Synthesis of polycardanol from a renewable resource using a fungal peroxidase from Coprinus cinereus [J].