From porphyrin sponges to porphyrin sieves: a unique crystalline lattice of aquazinc tetra(4-carboxyphenyl)porphyrin with nanosized channels

被引：102

作者：

Diskin-Posner, Y ^{[1
]}

Goldberg, I ^{[1
]}

机构：

[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a906085e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A unique supramolecular solid assembly with very wide channels has been formulated with aquazinc tetra(4-carboxyphenyl)porphyrin building blocks; the open porphyrin lattice is sustained by characteristic stacking interactions and multiple hydrogen bonding, it comprises only about 39% of the crystal volume, and preserves its crystallinity up to about 360 K.

引用

页码：1961 / 1962

页数：2

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