The electrochemical oxidation of tetrahydrofuran in sulphuric acid solution

被引：18

作者：

Avgousti, C

Georgolios, N

Kyriacou, G

Ritzoulis, G ^{[1
]}

机构：

[1] Aristotelian Univ Salonika, Dept Chem, Phys Chem Lab, GR-54006 Salonika, Greece

[2] Aristotelian Univ Salonika, Dept Chem Engn, Inorgan Chem Lab, GR-54006 Salonika, Greece

来源：

ELECTROCHIMICA ACTA | 1999年 / 44卷 / 19期

关键词：

tetrahydrofuran; gamma-butyrolactone; succinic acid; electrochemical oxidation; GC-MS; underpotential deposition;

D O I：

10.1016/S0013-4686(99)00051-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical behaviour of THF on Pt in H2SO4 using cyclic voltammetry was examined. The products were identified with GC-MS, The two basic products were found to be gamma-butyrolactone and 2-hydroxytetrahydrofuran with current efficiencies up to 54.4 and 41.2% correspondingly. In addition, the UPD of Tl and Cu were shown to inhibit THF oxidation, since the deposits probably block active sites on the electrode surface. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3295 / 3301

页数：7

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