Recent Advances in Polycarbonate Recycling: A Review of Degradation Methods and Their Mechanisms

被引:147
作者
Antonakou, E. V. [1 ]
Achilias, D. S. [1 ]
机构
[1] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece
关键词
Polycarbonate; Recycling; WEEE; Pyrolysis; Bisphenol-A; THERMAL-DECOMPOSITION PROCESSES; BISPHENOL-A POLYCARBONATE; CATALYZED DEGRADATION; CHEMICAL CONVERSION; BIOMASS PYROLYSIS; PLASTIC WASTES; DEPOLYMERIZATION; KINETICS; BLENDS; POLY(CARBONATE);
D O I
10.1007/s12649-012-9159-x
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Polycarbonate, poly(bisphenol A carbonate), PC, is an important engineering polymer with a variety of optical and technical applications, whose demand is increasing year by year. Its consumption in 2008 was estimated to have reached 3.3 Mt and to increase by a 7 % per year. The three different routes for PC recycling are: direct recycle (mechanical recycling or blending with other materials), treatment via chemical methods and thermo-chemical methods (pyrolysis). The aim of the current review paper is to visit all the available methods for PC recycling and their mechanisms and record their potential and weaknesses. Apart from methods such as pyrolysis and degradation via chemical routes, novel methods, such as decomposition in the presence of enzymes, are been reported. Finally, the main degradation methods of PC blends and WEEEs applications are also been presented.
引用
收藏
页码:9 / 21
页数:13
相关论文
共 80 条
[41]   Kinetics and mechanism of p-isopropenylphenol synthesis via hydrothermal cleavage of bisphenol A [J].
Hunter, SE ;
Savage, PE .
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (14) :4724-4731
[42]   The thermal degradation of bisphenol A polycarbonate in air [J].
Jang, BN ;
Wilkie, CA .
THERMOCHIMICA ACTA, 2005, 426 (1-2) :73-84
[43]   A TGA/FTIR and mass spectral study on the thermal degradation of bisphenol A polycarbonate [J].
Jang, BN ;
Wilkie, CA .
POLYMER DEGRADATION AND STABILITY, 2004, 86 (03) :419-430
[44]   Thermal stability of polycarbonate composites reinforced with potassium titanate whiskers: effect of coupling agent addition [J].
Jiang, W ;
Tjong, SC .
POLYMER DEGRADATION AND STABILITY, 1999, 66 (02) :241-246
[45]   Study on depolymerization of polycarbonate in supercritical ethanol [J].
Jie, Huang ;
Ke, Huang ;
Qing, Zhou ;
Lei, Chen ;
Wu Yongqiang ;
Zhu Zibin .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (10) :2307-2314
[46]   Acid- and base-catalyzed hydrolyses of aliphatic polycarbonates and polyesters [J].
Jung, Jae Hwan ;
Ree, Moonhor ;
Kim, Heesoo .
CATALYSIS TODAY, 2006, 115 (1-4) :283-287
[47]   Chemical modification of poly(vinyl chloride) by nucleophilic substitution [J].
Kameda, Tomohito ;
Ono, Masahiko ;
Grause, Guido ;
Mizoguchi, Tadaaki ;
Yoshioka, Toshiaki .
POLYMER DEGRADATION AND STABILITY, 2009, 94 (01) :107-112
[48]   Chemical recycling of poly(ethylene terephthalate) [J].
Karayannidis, George P. ;
Achilias, Dimitris S. .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2007, 292 (02) :128-146
[49]   Ab initio study on thermal degradation reactions of polycarbonate [J].
Katajisto, J ;
Pakkanen, TT ;
Pakkanen, TA ;
Hirva, P .
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2003, 634 :305-310
[50]   Kinetics of Polycarbonate Methanolysis by a Consecutive Reaction Model [J].
Kim, Dongpil ;
Kim, Bo-kyung ;
Cho, Youngmin ;
Han, Myungwan ;
Kim, Beom-Sik .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (14) :6591-6599