Kinetically Controlled Crystallization for Synthesis of Monodispersed Coordination Polymer Nanocubes and Their Self-Assembly to Periodic Arrangements

被引：133

作者：

Hu, Ming ^{[1
]}

Ishihara, Shinsuke ^{[1
]}

Ariga, Katsuhiko ^{[1
]}

Imura, Masataka ^{[1
]}

Yamauchi, Yusuke ^{[1
,2
,3
]}

机构：

[1] Natl Inst Mat Sci, World Premier Int, Res Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan

[2] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan

[3] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 06期

关键词：

crystallization; coordination polymers; nanoporous materials; self-assembly; METAL-ORGANIC FRAMEWORKS; PRUSSIAN BLUE NANOPARTICLES; COMPLEXES; SIZE; FABRICATION; CRYSTALS; ANALOGS; SYSTEMS; ION; MN;

D O I：

10.1002/chem.201203138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under control: A new concept for synthesizing monodispersed coordination polymer (CP) nanoparticles is established. By utilizing a chelating agent that is coordinated to the metal ions, the subsequent coordination process between metal ions and ligands is controllable (see figure). The obtained nanocubes with uniform sizes can be self-assembled into periodically ordered arrangements. This phenomenon is useful for sensing applications, such as those with responsive photonic crystals. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1882 / 1885

页数：4

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