Hierarchical self-assembly of p-terphenyl derivative with dumbbell-like amphiphilic and rod-coil characteristics

被引:15
作者
Zhou, Qilong [1 ,2 ]
Chen, Ting [1 ,2 ]
Zhang, Jintao [1 ,2 ]
Wan, Lijun [1 ]
Xie, Ping [1 ]
Han, Charles C. [1 ]
Yan, Shouke [1 ]
Zhang, Rongben [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
amphiphile; nanorod; rod-coil; self-assembly;
D O I
10.1016/j.tetlet.2008.07.048
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
As water is gradually added, a p-terphenyl derivative with dumbbell-like amphiphilic and rod-coil characteristics can hierarchically self-assemble to metastable rectangle columns architecting sheets first and then to stable quasi-hexagonal columns architecting rolled sheets, and finally to rod-like nanostructures in MeOH/H2O solution. Interestingly, the formed sheet, rolled sheet, and nanorod possess blue-light emitting property. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5522 / 5526
页数:5
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