Correlation of kinetic and thermodynamic quantities of Tl(I)/Tl(Hg) electroreduction with parameters of binary mixtures of water with acetone, acetonitrile, methanol, and N,N-dimethylformamide

被引：8

作者：

Anastopoulos, AG ^{[1
]}

Latsinoglou, T ^{[1
]}

机构：

[1] Aristotle Univ Thessaloniki, Dept Chem, Phys Chem Lab, Thessaloniki 54124, Greece

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2005年 / 34卷 / 12期

关键词：

thallium electroreduction; binary mixtures; kinetic; thermodynamic parameters; solvatochromic parameters;

D O I：

10.1007/s10953-005-8507-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The diffusion coefficient of Tl+ ions, the standard potential, the size factor of the activated complex, and the standard rate constant of the overall reaction Tl(I)/Tl(Hg) in aqueous mixtures of acetone, methanol, acetonitrile, and dimethylformamide are related to parameters representing the composition, polarity, electron pair, and hydrogen-bond donor ability of these mixtures. The dependencies on mixture composition, and the linear and multilinear correlation with solvatochromic parameters are interpreted by assuming a heterosolvation effect in combination with a two-step ion transfer - ion adsorption mechanism.

引用

页码：1341 / 1356

页数：16

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