Seashore mallow (Kosteletzkya pentacarpos) as a salt-tolerant feedstock for production of biodiesel and ethanol

被引:21
作者
Moser, Bryan R. [1 ]
Dien, Bruce S. [2 ]
Seliskar, Denise M. [3 ]
Gallagher, John L. [3 ]
机构
[1] ARS, Biooils Res Unit, Natl Ctr Agr Utilizat Res, USDA, Peoria, IL 61604 USA
[2] ARS, Bioenergy Res Unit, Natl Ctr Agr Utilizat Res, USDA, Peoria, IL 61604 USA
[3] Univ Delaware, Halophyte Biotechnol Ctr, Coll Earth Ocean & Environm, Lewes, DE 19958 USA
关键词
Biodiesel; Ethanol; Kosteletzkya pentacarpos; Saccharomyces cerevisiae; Seashore mallow; METHYL-ESTERS; FUEL PROPERTIES; FATTY-ACID; OIL; PRETREATMENT; VIRGINICA; SEED; FERMENTATION; INHIBITION; CONVERSION;
D O I
10.1016/j.renene.2012.08.016
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Seashore mallow (Kosteletzkya pentacarpos) is a non-invasive perennial nonclonal halophytic oilseed-producing dicot that was investigated as a feedstock for production of biodiesel from seeds and ethanol from residual stem biomass. Seashore mallow seeds contained 19.3 mass % oil, which after extraction with hexane and pretreatment with catalytic sulfuric acid was converted into methyl esters in 94 mass % yield utilizing homogenous base catalysis. The principal components identified were methyl linoleate (48.9%), palmitate (24.4%) and oleate (18.3%). Fuel properties were characterized and compared to biodiesel standards ASTM D6751 and EN 14214. Also investigated were blends with petrodiesel. Lastly, seashore mallow stems were rich in neutral carbohydrates (51.8 mass %). After simultaneous saccharification and fermentation employing a native Saccharomyces cerevisiae yeast strain, the stems provided ethanol and xylose yields of 104 g/kg and 47.8 g/kg, respectively. Of the four pretreatment methodologies explored, dilute ammonium hydroxide provided the highest yield of sugars. Published by Elsevier Ltd.
引用
收藏
页码:833 / 839
页数:7
相关论文
共 32 条
[1]   Innovations in Hibiscus and Kosteletzkya (Malvaceae, hibisceae) [J].
Blanchard, Orland J., Jr. .
NOVON, 2008, 18 (01) :4-8
[2]  
Dien B S., 2009, The Alcohol Text Book, V5th, P73
[3]   Chemical composition and response to dilute-acid pretreatment and enzymatic saccharification of alfalfa, reed canarygrass, and switchgrass [J].
Dien, Bruce S. ;
Jung, Hans-Joachim G. ;
Vogel, Kenneth P. ;
Casler, Michael D. ;
Lamb, JoAnn F. S. ;
Iten, Loren ;
Mitchell, Robert B. ;
Sarath, Gautum .
BIOMASS & BIOENERGY, 2006, 30 (10) :880-891
[4]   Enhancing alfalfa conversion efficiencies for sugar recovery and ethanol production by altering lignin composition [J].
Dien, Bruce S. ;
Miller, David J. ;
Hector, Ronald E. ;
Dixon, Richard A. ;
Chen, Fang ;
McCaslin, Mark ;
Reisen, Peter ;
Sarath, Gautam ;
Cotta, Michael A. .
BIORESOURCE TECHNOLOGY, 2011, 102 (11) :6479-6486
[5]   Improved Sugar Conversion and Ethanol Yield for Forage Sorghum (Sorghum bicolor L. Moench) Lines with Reduced Lignin Contents [J].
Dien, Bruce S. ;
Sarath, Gautam ;
Pedersen, Jeffrey F. ;
Sattler, Scott E. ;
Chen, Han ;
Funnell-Harris, Deanna L. ;
Nichols, Nancy N. ;
Cotta, Michael A. .
BIOENERGY RESEARCH, 2009, 2 (03) :153-164
[6]  
Dien BS, INT J LOW C IN PRESS
[7]   Crystallization behavior of fatty acid methyl esters [J].
Dunn, Robert O. .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2008, 85 (10) :961-972
[8]   VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].
FREEDMAN, B ;
PRYDE, EH ;
MOUNTS, TL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643
[9]   HALOPHYTIC CROPS FOR CULTIVATION AT SEAWATER SALINITY [J].
GALLAGHER, JL .
PLANT AND SOIL, 1985, 89 (1-3) :323-336
[10]  
Gould MJ, 1984, BIOTECHNOL BIOENG, V26, P46