Dielectric relaxation study of alcohol/diol(s) mixtures

被引:34
作者
Hanna, FF
Gestblom, B
Soliman, A
机构
[1] Natl Res Ctr, Microwave Phys Dept, Cairo 12311, Egypt
[2] Univ Uppsala, Dept Phys, S-75121 Uppsala, Sweden
[3] La Trobe Univ, Dept Phys, Bundoora, Vic 3086, Australia
关键词
dielectric spectroscopy; time domain spectroscopy (TDS); diol; alcohol; hydrogen bonding and diol(s)/alcohol mixtures;
D O I
10.1016/S0167-7322(01)00284-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dielectric relaxation of binary and ternary diol(s)/alcohol mixtures has been studied. Diols of different chain length namely 1,2 ethanediol, 1,3 propanediol, 1,4 butanediol and 1.5 pentanediol are used. The monohydric alcohols used are benzyl, n-hexyl, cyclopentyl, cyclohexyl and cycloheptyl alcohol. The relaxation spectra have been analyzed in one Cole-Davidson term. An apparent dipole moment term and the effective relaxation time of the main dispersion region are given as function or the number density of dipoles N-D.
引用
收藏
页码:27 / 40
页数:14
相关论文
共 48 条
[1]  
ANDREY KL, 1993, T FARADAY SOC, V89, P1985
[2]  
BEINE AH, 1988, THESIS U MUNSTER GER
[3]   THE DIELECTRIC-PROPERTIES OF ALCOHOLS WATER SOLUTIONS .1. THE ALCOHOL RICH REGION [J].
BERTOLINI, D ;
CASSETTARI, M ;
SALVETTI, G .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (01) :365-372
[4]   DIELECTRIC RELAXATION OF 1-BUTANOL AND 1-DECANOL IN SEVERAL SOLVENTS [J].
CROSSLEY, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (12) :1790-&
[5]   DIELECTRIC RELAXATION IN ISOMERIC OCTYL ALCOHOLS [J].
DANNHAUS.W .
JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (05) :1918-&
[6]  
Dannhauser W., 1970, PHYS CHEM LIQ, V2, P37
[7]   INVESTIGATION OF STRUCTURE, DYNAMICS, AND SOLVATION IN 1-OCTANOL AND ITS WATER-SATURATED SOLUTION - MOLECULAR-DYNAMICS AND FREE-ENERGY PERTURBATION STUDIES [J].
DEBOLT, SE ;
KOLLMAN, PA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5316-5340
[8]   DIELECTRIC PROPERTIES OF METHANOL AND METHANOL-1-PROPANOL SOLUTIONS [J].
DENNEY, DJ ;
COLE, RH .
JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (10) :1767-1772
[9]   MICROWAVE ABSORPTION AND MOLECULAR STRUCTURE IN LIQUIDS .62. 3 DIELECTRIC DISPERSION REGIONS OF NORMAL PRIMARY ALCOHOLS [J].
GARG, SK ;
SMYTH, CP .
JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (04) :1294-&