Integrated direct contact membrane distillation for olive mill wastewater treatment

被引:113
作者
El-Abbassi, A. [1 ]
Hafidi, A. [1 ]
Khayet, M. [2 ]
Garcia-Payo, M. C. [2 ]
机构
[1] Semlalia, Fac Sci, Dept Biol, Food Sci Lab, Marrakech 40090, Morocco
[2] Univ Complutense Madrid, Fac Phys, Dept Appl Phys 1, E-28040 Madrid, Spain
关键词
Direct contact membrane distillation; Integrated system; Olive mill wastewater; Phenolic compounds; Membrane fouling; Concentration factor; ANAEROBIC-DIGESTION; PHENOLIC-COMPOUNDS; POLYPHENOLS; WASTEWATERS; DECOLOURIZATION; FRACTIONATION; ANTIOXIDANTS; RECOVERY; REMOVAL; OILS;
D O I
10.1016/j.desal.2012.06.014
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Direct contact membrane distillation (DCMD) process was applied for olive mill wastewater (OMW) treatment and its concentration using a commercial flat-sheet polytetrafluoroethylene membrane (TF200, Gelman) with 0.2 mu m mean pore size. The effects of the mean temperature and temperature difference on the DCMD permeate flux were studied. Two pre-treatment processes, coagulation/flocculation and microfiltration (MF), were considered and the effects of each one on the DCMD performance were investigated. MF was found to be the optimum pre-treatment to be integrated to DCMD for OMW. When the permeate temperature was kept constant at 20 degrees C, the DCMD permeate flux increased with the increase of the feed temperature. However, the permeate flux decreased with the feed phenol concentration of OMW. The concentration factor of each phenolic compound varied from 1.56 to 2.93. The main phenolic compound in the tested OMW samples was found to be the hydroxytyrosol, which was concentrated more than two times from 4.01 g/L to 8.16 g/L after 40 h of OMW processing by DCMD. The membrane fouling phenomenon was also studied. Results showed that the integrated MF/DCMD can be an effective process for the treatment and concentration of OMW obtaining clean water and a phenolic-rich concentrate. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:31 / 38
页数:8
相关论文
共 38 条
[1]   Decolourization and removal of phenolic compounds from olive mill wastewater by electrocoagulation [J].
Adhoum, N ;
Monser, L .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2004, 43 (10) :1281-1287
[2]   Investigation of two ultrafiltration membranes for treatment of olive oil mill wastewater [J].
Akdemir, Ezgi Oktav ;
Ozer, Adem .
DESALINATION, 2009, 249 (02) :660-666
[3]  
APHA American Public Health Association, 1981, STANDARD METHODS EXA, P77
[4]  
Aubert G., 1978, METHODES ANAL SOLS, P189
[5]   ANAEROBIC-DIGESTION OF BLACK-OLIVE WASTE-WATER [J].
BORJA, R ;
MARTIN, A ;
GARRIDO, A .
BIORESOURCE TECHNOLOGY, 1993, 45 (01) :27-32
[6]   Effect of storage on refined and husk olive oils composition: Stabilization by addition of natural antioxidants from Chemlali olive leaves [J].
Bouaziz, Mohamed ;
Fki, Ines ;
Jemai, Hedya ;
Ayadi, Mohamed ;
Sayadi, Sami .
FOOD CHEMISTRY, 2008, 108 (01) :253-262
[7]  
BRADFORD MM, 1976, ANAL BIOCHEM, V72, P248, DOI 10.1016/0003-2697(76)90527-3
[8]  
CHIMI H, 1990, REV FR CORPS GRAS, V37, P363
[9]   Treatment of olive mill wastewaters by nanofiltration and reverse osmosis membranes [J].
Coskun, Tamer ;
Debik, Eyup ;
Demir, Neslihan Manav .
DESALINATION, 2010, 259 (1-3) :65-70
[10]   Characterization and fractionation of phenolic compounds extracted from olive oil mill wastewaters [J].
De Marco, Elena ;
Savarese, Maria ;
Paduano, Antonello ;
Sacchi, Raffaele .
FOOD CHEMISTRY, 2007, 104 (02) :858-867