Multicomponent Assembly of Heterometallic Isosceles Triangles

被引：59
作者：
Schmittel, Michael [1 ]
Mahata, Kingsuk [1 ]
机构：
[1] Univ Siegen, Ctr Micro & Nanochem & Engn, D-57068 Siegen, Germany
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 03期
关键词：
COORDINATION; MACROCYCLES; RECOGNITION; ZINC(II); CORNERS; BONDS;
D O I：
10.1021/ic8021084
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The multicomponent synthesis and solution-state characterization of three supramolecular bis-heterometallic isosceles triangles are elaborated. The triangular assemblies are isosceles both geometrically and chemically; they comprise multiple ligands, metals, and binding motifs. Variation of the length of one side of the triangle by changing the number of phenyl spacers n = 0, 1, and 2 influences the redox potential of the opposing copper(I) center, allowing translation of the nanomechanical changes into electronically readable values.
引用
收藏
页码：822 / 824
页数：3
相关论文
共 39 条
[1]   Novel crown ether and salen metal chelation driven molecular pincers [J].
Abe, Aki M. M. ;
Helaja, Juho ;
Koskinen, Ari M. P. .
ORGANIC LETTERS, 2006, 8 (20) :4537-4540
[2]  
ARNBUNDO EA, 1999, INORG CHEM, V38, P4233
[3]   A highly rigid ditopic conjugate with orthogonal coordination axes and its zinc(II) and copper(II) complexes [J].
Champin, Benoit ;
Sartor, Valerie ;
Sauvage, Jean-Pierre .
NEW JOURNAL OF CHEMISTRY, 2008, 32 (06) :1048-1054
[4]   Molecular Borromean rings [J].
Chichak, KS ;
Cantrill, SJ ;
Pease, AR ;
Chiu, SH ;
Cave, GWV ;
Atwood, JL ;
Stoddart, JF .
SCIENCE, 2004, 304 (5675) :1308-1312
[5]  
CHRISTINAT N, 2008, CHEM-EUR J, V47, P1848
[6]   Self-assembly of a copper(II)-based metallosupramolecular hexagon [J].
Coronado, Eugenio ;
Galan-Mascaros, Jose Ramon ;
Gavina, Pablo ;
Marti-Gastaldo, Carlos ;
Romero, Francisco M. ;
Tatay, Sergio .
INORGANIC CHEMISTRY, 2008, 47 (12) :5197-5203
[7]   Chiral organometallic triangles with Rh-Rh bonds.: 1.: Compounds prepared from racemic cis-Rh2(C6H4PPh2)2(OAc)2 [J].
Cotton, FA ;
Murillo, CA ;
Wang, XP ;
Yu, RM .
INORGANIC CHEMISTRY, 2004, 43 (26) :8394-8403
[8]   Supramolecular assemblies of trinuclear triangular copper(II) secondary building units through hydrogen bonds. Generation of different metal-organic frameworks, valuable catalysts for peroxidative oxidation of alkanes [J].
Di Nicola, Corrado ;
Karabach, Yauhen Yu. ;
Kirillov, Alexander M. ;
Monari, Magda ;
Pandolfo, Luciano ;
Pettinari, Claudio ;
Pombeiro, Armando J. L. .
INORGANIC CHEMISTRY, 2007, 46 (01) :221-230
[9]   Synthesis and applications of supramolecular porphyrinic materials [J].
Drain, CM ;
Goldberg, I ;
Sylvain, I ;
Falber, A .
FUNCTIONAL MOLECULAR NANOSTRUCTURES, 2005, 245 :55-88
[10]   Self-assembly reactions between the cis-protected metal corners (N-N)MII (N-N = ethylenediamine, 4,4′-substituted 2,2′-bipyridine; M = Pd, Pt) and the fluorinated edge 1,4-bis(4-pyridyl)tetrafluorobenzene [J].
Ferrer, Montserrat ;
Gutierrez, Albert ;
Mounir, Mounia ;
Rossell, Oriol ;
Ruiz, Eliseo ;
Rang, Alexander ;
Engeser, Marianne .
INORGANIC CHEMISTRY, 2007, 46 (08) :3395-3406
1234