Hybrid Nanostructures of MoS2/Sisal Fiber Tubular Carbon as Anode Material for Lithium ion Batteries

被引:12
作者
Liu, Yuanzhou [1 ]
Qin, Aimiao [1 ]
Chen, Shuoping [1 ]
Liao, Lei [2 ]
Zhang, Kaiyou [1 ]
Mo, Zilin [1 ]
机构
[1] Guilin Univ Technol, Coll Mat Sci & Engn, Key Lab New Proc Technol Nonferrous Met & Mat, Minist Educ,Guangxi Key Lab Univ Clean Met & Comp, Guilin, Peoples R China
[2] Guilin Univ Technol, Coll Environm Sci & Engn, Guangxi Key Lab Environm Pollut Control Theory &, Guilin, Peoples R China
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2018年 / 13卷 / 02期
基金
中国国家自然科学基金;
关键词
Sisal fiber tubular carbon; Hydrothermal-anneal; MoS2; nanosheets; Nanohybrids; Lithium ion batteries; CAPACITIVE ENERGY-STORAGE; MOLYBDENUM-DISULFIDE MOS2; FEW-LAYER MOS2; GRAPHENE NANOSHEETS; WHEAT-STRAW; BINDER-FREE; PERFORMANCE; MICROSPHERES; EVOLUTION; GROWTH;
D O I
10.20964/2018.02.63
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Environmentally friendly and low-cost MoS2/sisal fiber tubular carbon (MoS2/SFTC) nanohybrids have been prepared via a facile hydrothermal-anneal strategy, in which the tubular biomass carbon derived from natural sisal fibers as a conductive base. The as-prepared nanohybrids are characterized by Raman spectra, XRD, XPS, FESEM, TEM and EDS. It is shown that the sisal fiber tubular carbons with nanowrinkles and nanofolds were uniformly coated with vertical MoS2 nanosheets on the surface. As an anode material for lithium ion batteries, the MoS2/SFTC nanohybrids possess an excellent cycling performance, superior rate capability and high reversible capacity. A reversible specific capacity of 437.2 mA h g(-1) is maintained after 50 cycles at the current density of 50 mA g(-1). Even at a high current density of 2000 mA g(-1), the reversible specific capacity could be retained at 241.1 mA h g(-1). The superior electrochemical performance of the MoS2/SFTC nanohybrids can be attributed to the synergistic effects of uniform vertical MoS2 nanosheets and conductive SFTC nanostructures.
引用
收藏
页码:2054 / 2068
页数:15
相关论文
共 67 条
  • [1] PROPERTIES OF SISAL-CNSL COMPOSITES
    BISANDA, ETN
    ANSELL, MP
    [J]. JOURNAL OF MATERIALS SCIENCE, 1992, 27 (06) : 1690 - 1700
  • [2] Ultrathin MoS2/Nitrogen-Doped Graphene Nanosheets with Highly Reversible Lithium Storage
    Chang, Kun
    Geng, Dongsheng
    Li, Xifei
    Yang, Jinli
    Tang, Yongji
    Cai, Mei
    Li, Ruying
    Sun, Xueliang
    [J]. ADVANCED ENERGY MATERIALS, 2013, 3 (07) : 839 - 844
  • [3] Single-layer MoS2/graphene dispersed in amorphous carbon: towards high electrochemical performances in rechargeable lithium ion batteries
    Chang, Kun
    Chen, Weixiang
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (43) : 17175 - 17184
  • [4] Facile synthesis of 3D few-layered MoS2 coated TiO2 nanosheet core-shell nanostructures for stable and high-performance lithium-ion batteries
    Chen, Biao
    Zhao, Naiqin
    Guo, Lichao
    He, Fang
    Shi, Chunsheng
    He, Chunnian
    Li, Jiajun
    Liu, Enzuo
    [J]. NANOSCALE, 2015, 7 (30) : 12895 - 12905
  • [5] Hierarchically porous nitrogen-rich carbon derived from wheat straw as an ultra-high-rate anode for lithium ion batteries
    Chen, Li
    Zhang, Yongzhi
    Lin, Chaohong
    Yang, Wen
    Meng, Yan
    Guo, Yong
    Li, Menglong
    Xiao, Dan
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (25) : 9684 - 9690
  • [6] Mechanically-induced reverse phase transformation of MoS2 from stable 2H to metastable 1T and its memristive behavior
    Cheng, Peifu
    Sun, Kai
    Hu, Yun Hang
    [J]. RSC ADVANCES, 2016, 6 (70) : 65691 - 65697
  • [7] Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/NCHEM.1589, 10.1038/nchem.1589]
  • [8] XPS study of as-prepared and reduced molybdenum oxides
    Choi, JG
    Thompson, LT
    [J]. APPLIED SURFACE SCIENCE, 1996, 93 (02) : 143 - 149
  • [9] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
    Coleman, Jonathan N.
    Lotya, Mustafa
    O'Neill, Arlene
    Bergin, Shane D.
    King, Paul J.
    Khan, Umar
    Young, Karen
    Gaucher, Alexandre
    De, Sukanta
    Smith, Ronan J.
    Shvets, Igor V.
    Arora, Sunil K.
    Stanton, George
    Kim, Hye-Young
    Lee, Kangho
    Kim, Gyu Tae
    Duesberg, Georg S.
    Hallam, Toby
    Boland, John J.
    Wang, Jing Jing
    Donegan, John F.
    Grunlan, Jaime C.
    Moriarty, Gregory
    Shmeliov, Aleksey
    Nicholls, Rebecca J.
    Perkins, James M.
    Grieveson, Eleanor M.
    Theuwissen, Koenraad
    McComb, David W.
    Nellist, Peter D.
    Nicolosi, Valeria
    [J]. SCIENCE, 2011, 331 (6017) : 568 - 571
  • [10] Growth of MoS2@C nanobowls as a lithium-ion battery anode material
    Cui, Chunyu
    Li, Xiu
    Hu, Zhe
    Xu, Jiantie
    Liu, Huakun
    Ma, Jianmin
    [J]. RSC ADVANCES, 2015, 5 (112): : 92506 - 92514