Stability limits for the horizontal ribbon growth of silicon crystals

被引:18
作者
Daggolu, Parthiv [1 ]
Yeckel, Andrew [1 ]
Bleil, Carl E. [2 ]
Derby, Jeffrey J. [1 ]
机构
[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA
[2] Energy Mat Res LLC, Rochester Hills, MI 48309 USA
基金
美国国家科学基金会;
关键词
Computer simulation; Fluid flows; Heat transfer; Edge defined film fed growth; Semiconducting silicon; Solar cells; HEAT-FLOW; SURFACE; ANGLE;
D O I
10.1016/j.jcrysgro.2012.10.024
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A rigorous, thermal-capillary model, developed to couple heat transfer, melt convection and capillary physics, is employed to assess stability limits of the HRG system for growing silicon ribbons. Extending the prior understanding of this process put forth by Daggolu et al. [Thermal-capillary analysis of the horizontal ribbon growth of silicon crystals, Journal of Crystal Growth 355 (2012)129-139], model results presented here identify additional failure mechanisms, including the bridging of crystal onto crucible, the spilling of melt from the crucible, and the undercooling of melt at the ribbon tip, that are consistent with prior experimental observations. Changes in pull rate, pull angle, melt height, and other parameters are shown to give rise to limits, indicating that only narrow operating windows exist in multi-dimensional parameter space for stable growth conditions that circumvent these failure mechanisms. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:132 / 140
页数:9
相关论文
共 35 条
[1]   Simulation of the crystallisation of silicon ribbons on substrate [J].
Apel, M ;
Franke, D ;
Steinbach, I .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2002, 72 (1-4) :201-208
[2]  
Bates H. E., 1981, Fifteenth IEEE Photovoltaic Specialists Conference - 1981, P255
[3]   Growth of silicon sheets for photovoltaic applications [J].
Bell, RO ;
Kalejs, JP .
JOURNAL OF MATERIALS RESEARCH, 1998, 13 (10) :2732-2739
[4]  
Bleil C. E., 1969, Journal of Crystal Growth, V5, P99, DOI 10.1016/0022-0248(69)90020-7
[5]  
Bleil C.E., 1972, US patent, Patent No. 3681033
[6]  
Christodoulou K.N., 1997, LIQUID FILM COATING, P297
[7]   DISCRETIZATION OF FREE-SURFACE FLOWS AND OTHER MOVING BOUNDARY-PROBLEMS [J].
CHRISTODOULOU, KN ;
SCRIVEN, LE .
JOURNAL OF COMPUTATIONAL PHYSICS, 1992, 99 (01) :39-55
[8]   TECHNIQUES FOR THE CRYSTAL-GROWTH OF SILICON INGOTS AND RIBBONS [J].
CISZEK, TF .
JOURNAL OF CRYSTAL GROWTH, 1984, 66 (03) :655-672
[9]  
Daggolu P., THESIS U MINNESOTA
[10]   Thermal-capillary analysis of the horizontal ribbon growth of silicon crystals [J].
Daggolu, Parthiv ;
Yeckel, Andrew ;
Bleil, Carl E. ;
Derby, Jeffrey J. .
JOURNAL OF CRYSTAL GROWTH, 2012, 355 (01) :129-139